MOHAMED, Walid Fathalla, Michal ČAJAN, Jaromír MAREK and Pavel PAZDERA. The Reactivity Study on N3,N3-(3-Oxapentan-1,5-diyl)-N1-(2-phenyl-3,4-dihydroquinazolin-4-yliden)thiourea. In Proceedings of ECSOC-5, The Fifth International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-5.htm. 1st ed. Basel: MDPI, Basel, Switzerland, 2001, p. [a0049], 1 pp. ISBN 3-906980-06-5.
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Basic information
Original name The Reactivity Study on N3,N3-(3-Oxapentan-1,5-diyl)-N1-(2-phenyl-3,4-dihydroquinazolin-4-yliden)thiourea
Authors MOHAMED, Walid Fathalla, Michal ČAJAN, Jaromír MAREK and Pavel PAZDERA.
Edition 1. vyd. Basel, Proceedings of ECSOC-5, The Fifth International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-5.htm, p. [a0049], 1 pp. 2001.
Publisher MDPI, Basel, Switzerland
Other information
Original language English
Type of outcome Proceedings paper
Field of Study 10401 Organic chemistry
Country of publisher Switzerland
Confidentiality degree is not subject to a state or trade secret
WWW URL
RIV identification code RIV/00216224:14310/01:00005300
Organization unit Faculty of Science
ISBN 3-906980-06-5
Keywords in English Quinazolines; thioureas; domino-reactions; N3;N3-(3-oxapentan-1;5-diyl)-N1-(2-phenyl-3;4-dihydroquinazolin-4-ylidene)thiourea;
Tags 4-dihydroquinazolin-4-ylidene)thiourea, 5-diyl)-N1-(2-phenyl-3, domino-reactions, N3, N3-(3-oxapentan-1, quinazolines, thioureas
Changed by Changed by: doc. RNDr. Pavel Pazdera, CSc., učo 2276. Changed: 15/1/2002 11:26.
Abstract
The thioamide represented by the model compound N3,N3-(3-oxapentan-1,5-diyl)-N1-(2-phenyl-3,4-dihydro-quinazolin-4-ylidene)thiourea contain both multi-functional nucleophilic and electrophilic characters. It reacts regioselectivity with amines, amines in the presence of H2O2 and alkyl halides to give the transamination reaction products, the oxidative desulfurization products and the S-alkyl product, respectively. FTIR, 1H NMR, 13C NMR, mass spectroscopy and X-ray identified compounds.
Links
GA203/01/1333, research and development projectName: Chalkogenorganické sloučeniny - příprava, transformace a strukturní studie
Investor: Czech Science Foundation, Chalcogen organic compounds - synthesis, transformation and structure elucidation
MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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