J 2002

Influence of N-Substituents of Carbamoyl-stabilized Azomethine Ylides in 1,3-Dipolar Cycloadditions

POSPÍŠIL, Jiří, Martin TRÁVNÍČEK and Milan POTÁČEK

Basic information

Original name

Influence of N-Substituents of Carbamoyl-stabilized Azomethine Ylides in 1,3-Dipolar Cycloadditions

Authors

POSPÍŠIL, Jiří (203 Czech Republic), Martin TRÁVNÍČEK (203 Czech Republic) and Milan POTÁČEK (203 Czech Republic, guarantor)

Edition

ARKIVOC, Florida, ARKAT-USA, 2002, 1424-6376

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

RIV identification code

RIV/00216224:14310/02:00005564

Organization unit

Faculty of Science

Keywords in English

1;3-Dipolar cycloaddition; azomethine ylides; N-substituted 2-bromoacetamides; phenanthridinium salts; pyrrolidino[1;2-f]phenanthridines

Tags

Změněno: 18/3/2002 11:52, prof. RNDr. Milan Potáček, CSc.

Abstract

V originále

Upon treatment with base N-substituted carbamoylmethylphenanthridinium salts were converted into azomethine ylides. These intermediates were intercepted with symmetrically substituted dipolarophiles, and the stereochemistry of the cycloadducts has been found to be dependent on the substitution at the amide nitrogen atom.

Links

MSM 143100011, plan (intention)
Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles