Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate

RAKOVSKÝ, E.; L. ŽURKOVÁ and Jaromír MAREK. Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate. Monatshefte fuer Chemie, Chemical Monthly. Wien: Springer-Verlag, 2002, vol. 133, No 3, p. 177-183. ISSN 0026-9247.

Basic information

Original name

Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate

Authors

RAKOVSKÝ, E.; L. ŽURKOVÁ and Jaromír MAREK ORCID

Edition

Monatshefte fuer Chemie, Chemical Monthly, Wien, Springer-Verlag, 2002, 0026-9247

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Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Austria

Confidentiality degree

is not subject to a state or trade secret

Impact factor

Impact factor: 0.813

Organization unit

Faculty of Science

UT WoS

000174217600006

Keywords in English

THERMAL-BEHAVIOR; DECAVANADATES; PROTONATION; IR spectroscopy; X-Ray structure

Tags

DECAVANADATES, IR spectroscopy, PROTONATION, THERMAL-BEHAVIOR, X-RAY STRUCTURE

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Abstract

In the original language

Anhydrous 1,6-hexanediammonium dihydrogendecavanadate ((HdaH(2))(2)H2V10O28, 1) was prepared by reaction Of V2O5 with 1,6-hexanediamine in aqueous solution. The crystal structure of I was determined, and the proton positions in the H2V10O284- anion were calculated by the bond length/bond number method. The protons are bound to the centrosymmetrically oriented mu-OV3 groups of the decavanadate anion. Based on the analysis of IR spectra of 1 prepared from H2O and D2O, the absorption band at 871 cm(-1) can be attributed to delta(V-O-b-H) vibrations