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@inproceedings{484378, author = {Hasoň, Stanislav and Vetterl, Vladimír}, address = {Bratislava}, booktitle = {Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics}, keywords = {cytidine adsorption; deoxycytidine adsorption; two-dimensional condensation; Au(111);}, language = {eng}, location = {Bratislava}, pages = {110-110}, publisher = {XVI th International Symposium on Bioelectrochemistry and Bioenergetics}, title = {Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes}, year = {2001} }
TY - JOUR ID - 484378 AU - Hasoň, Stanislav - Vetterl, Vladimír PY - 2001 TI - Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes PB - XVI th International Symposium on Bioelectrochemistry and Bioenergetics CY - Bratislava KW - cytidine adsorption KW - deoxycytidine adsorption KW - two-dimensional condensation KW - Au(111); N2 - The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury film electrodes were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The kinetics of the interfacial rearrangements were better observed with the pyrolytic carbon than with glassy carbon electrodes. The experimental j-t and C-t curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type adsorption/desorption process. Adsorption of cytidine on Au(111) from 0.1 M KClO4 electrolyte solution is characterized by formation of various films delimited by 2-D phase transitions. ER -
HASOŇ, Stanislav a Vladimír VETTERL. Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes. In \textit{Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics}. Bratislava: XVI th International Symposium on Bioelectrochemistry and Bioenergetics, 2001, s.~110.
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