Two-dimensional condensation of nucleic acid components at
mercury film and gold electrodes

D 2001

Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes

HASOŇ, Stanislav and Vladimír VETTERL

Basic information

Original name

Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes

Authors

HASOŇ, Stanislav (203 Czech Republic) and Vladimír VETTERL (203 Czech Republic, guarantor)

Edition

Bratislava, Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics, p. 110-110, 2001

Publisher

XVI th International Symposium on Bioelectrochemistry and Bioenergetics

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10610 Biophysics

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

RIV identification code

RIV/00216224:14310/01:00007532

Organization unit

Faculty of Science

UT WoS

000176715700011

Keywords in English

cytidine adsorption; deoxycytidine adsorption; two-dimensional condensation; Au(111);

Abstract

V originále

The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury film electrodes were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The kinetics of the interfacial rearrangements were better observed with the pyrolytic carbon than with glassy carbon electrodes. The experimental j-t and C-t curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type adsorption/desorption process. Adsorption of cytidine on Au(111) from 0.1 M KClO4 electrolyte solution is characterized by formation of various films delimited by 2-D phase transitions.

Links

GV204/97/K084, research and development project

Name: Elektrody modifikované nukleovými kyselinami a bílkovinami. Nové nástroje v biochemickém a biomedicínském výzkumu

Investor: Czech Science Foundation, Electrodes modified with nucleic acids and proteins. New tools in biochemical and biomedical research

IAA4004002, research and development project

Name: Struktura a interakce nukleových kyselin a polypeptidů na površích kovů

Investor: Academy of Sciences of the Czech Republic, Structure and Interaction of Nucleic Acids on Metal Surfaces

IBS5004107, research and development project

Name: Aplikace biofyzikálních metod v biotechnologické a klinické praxi

Investor: Academy of Sciences of the Czech Republic, Application of biophysical methods in biotechnological and clinical praxis

Citovat

HASOŇ, Stanislav and Vladimír VETTERL. Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes. In Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics. Bratislava: XVI th International Symposium on Bioelectrochemistry and Bioenergetics, 2001, p. 110.

@inproceedings{484378,
   author = {Hasoň, Stanislav and Vetterl, Vladimír},
   address = {Bratislava},
   booktitle = {Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics},
   keywords = {cytidine adsorption; deoxycytidine adsorption; two-dimensional condensation; Au(111);},
   language = {eng},
   location = {Bratislava},
   pages = {110-110},
   publisher = {XVI th International Symposium on Bioelectrochemistry and Bioenergetics},
   title = {Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes},
   year = {2001}
}

TY  - JOUR
ID  - 484378
AU  - Hasoň, Stanislav - Vetterl, Vladimír
PY  - 2001
TI  - Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes
PB  - XVI th International Symposium on Bioelectrochemistry and Bioenergetics
CY  - Bratislava
KW  - cytidine adsorption
KW  - deoxycytidine adsorption
KW  - two-dimensional condensation
KW  - Au(111);
N2  - The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury film electrodes were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The kinetics of the interfacial rearrangements were better observed with the pyrolytic carbon than with glassy carbon electrodes. The experimental j-t and C-t curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type adsorption/desorption process. Adsorption of cytidine on Au(111) from 0.1 M KClO4 electrolyte solution is characterized by formation of various films delimited by 2-D phase transitions.
ER  -

HASOŇ, Stanislav and Vladimír VETTERL. Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes. In \textit{Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics}. Bratislava: XVI th International Symposium on Bioelectrochemistry and Bioenergetics, 2001, p.~110.

Detailed Information on Publication Record