J 2003

[N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate

MADEROVÁ, J.; Jaromír MAREK and F. PAVELČÍK

Basic information

Original name

[N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate

Authors

MADEROVÁ, J. (703 Slovakia); Jaromír MAREK (203 Czech Republic, guarantor) and F. PAVELČÍK (703 Slovakia)

Edition

Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2003, 0108-2701

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

Impact factor

Impact factor: 0.828

RIV identification code

RIV/00216224:14310/03:00008554

Organization unit

Faculty of Science

UT WoS

000182656300011

Keywords in English

structure; cobalt(III)
Changed: 31/5/2004 15:39, JUDr. Jarmila Friedmannová

Abstract

In the original language

The mononuclear title complex, [Co(C6H6NO6)(C2H8N2)].3H2O, contains an octahedrally coordinated Co(III) atom. The N-(carboxymethyl)aspartate moiety is coordinated as a tetradentate ligand, providing an OONO-donor set and forming two trans five-membered chelate rings and one six-membered chelate ring. A seven-membered chelate ring is also formed, which consists of part of the six-membered chelate ring and part of one of the five-membered chelate rings. The crystal structure of the complex is stabilized by hydrogen bonds with three water molecules.

Links

GA203/02/0436, research and development project
Name: Aplikace krystalografických databází ve vědecké praxi
MSM 143100005, plan (intention)
Name: Strukturně-funkční vztahy biomolekul a jejich role v metabolismu
Investor: Ministry of Education, Youth and Sports of the CR, Biomolecular Structure-function Relationships and their role in the Metabolism