Synthesis, structure and magnetic properties of a trinuclear
cyano-bridged complex
[Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2
{bappz=1,4-bis(3-aminopropyl)piperazine}

J 2003

Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine}

SMÉKAL, Z., Z. TRÁVNÍČEK, J. MROZINSKI a Jaromír MAREK

Základní údaje

Originální název

Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine}

Autoři

SMÉKAL, Z., Z. TRÁVNÍČEK, J. MROZINSKI a Jaromír MAREK

Vydání

Inorganic Chemistry Communications, Netherlands, Elsevier Science, 2003, 1387-7003

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.513

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Trinuclear complex; Copper(II); Nickel(II); Crystal structure; Magnetic properties

Štítky

Copper(II), Crystal Structure, magnetic properties, Nickel(II), Trinuclear complex

Změněno: 6. 10. 2003 16:12, doc. RNDr. Jaromír Marek, Ph.D.

Anotace

V originále

The bimetallic trinuclear complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 (bappz=1,4-bis(3-aminopropyl)piperazine) has been prepared from the reaction of [Cu(bappz)](ClO4)2 and K2[Ni(CN)4] in water and its crystal and molecular structure has been determined. The structure consists of a trinuclear [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)]2+ cation and two perchlorate anions. The bridging [Ni(CN)4]2- anion is coordinated by two [Cu(bappz)]2+ cations through two cyano groups, providing a novel trinuclear structure with the Cu-(NC)-Ni-(CN)-Cu linkage. The nickel(II) ion is four-coordinated by carbon atoms from four cyano groups (two of them, in trans position, form a bridge) in a square planar arrangement, whereas both the copper(II) ions are five-coordinated by four bappz nitrogens and one cyanide nitrogen in a distorted square-pyramidal geometry. The temperature dependence of magnetic susceptibility was measured for this compound over the range of 2-300 K. The magnetic investigation showed the presence of a very weak antiferromagnetic interaction (superexchange interaction parameter J=-0.54 cm-1) between the copper atoms through the diamagnetic [Ni(CN)4]2- ion.

Citovat

SMÉKAL, Z., Z. TRÁVNÍČEK, J. MROZINSKI a Jaromír MAREK. Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine}. Inorganic Chemistry Communications. Netherlands: Elsevier Science, 2003, roč. 6, č. 11, s. 1395-1399. ISSN 1387-7003.

@article{489254,
   author = {Smékal, Z. and Trávníček, Z. and Mrozinski, J. and Marek, Jaromír},
   article_location = {Netherlands},
   article_number = {11},
   keywords = {Trinuclear complex; Copper(II); Nickel(II); Crystal structure; Magnetic properties},
   language = {eng},
   issn = {1387-7003},
   journal = {Inorganic Chemistry Communications},
   title = {Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine}},
   volume = {6},
   year = {2003}
}

TY  - JOUR
ID  - 489254
AU  - Smékal, Z. - Trávníček, Z. - Mrozinski, J. - Marek, Jaromír
PY  - 2003
TI  - Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine}
JF  - Inorganic Chemistry Communications
VL  - 6
IS  - 11
SP  - 1395-1399
EP  - 1395-1399
PB  - Elsevier Science
SN  - 13877003
KW  - Trinuclear complex
KW  - Copper(II)
KW  - Nickel(II)
KW  - Crystal structure
KW  - Magnetic properties
N2  - The bimetallic trinuclear complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 (bappz=1,4-bis(3-aminopropyl)piperazine) has been prepared from the reaction of [Cu(bappz)](ClO4)2 and K2[Ni(CN)4] in water and its crystal and molecular structure has been determined. The structure consists of a trinuclear [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)]2+ cation and two perchlorate anions. The bridging [Ni(CN)4]2- anion is coordinated by two [Cu(bappz)]2+ cations through two cyano groups, providing a novel trinuclear structure with the Cu-(NC)-Ni-(CN)-Cu linkage. The nickel(II) ion is four-coordinated by carbon atoms from four cyano groups (two of them, in trans position, form a bridge) in a square planar arrangement, whereas both the copper(II) ions are five-coordinated by four bappz nitrogens and one cyanide nitrogen in a distorted square-pyramidal geometry. The temperature dependence of magnetic susceptibility was measured for this compound over the range of 2-300 K. The magnetic investigation showed the presence of a very weak antiferromagnetic interaction (superexchange interaction parameter J=-0.54 cm-1) between the copper atoms through the diamagnetic [Ni(CN)4]2- ion.
ER  -

SMÉKAL, Z., Z. TRÁVNÍČEK, J. MROZINSKI a Jaromír MAREK. Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(mu-NC)Ni(CN)2(mu-CN)Cu(bappz)](ClO4)2 $\{$bappz=1,4-bis(3-aminopropyl)piperazine$\}$. \textit{Inorganic Chemistry Communications}. Netherlands: Elsevier Science, 2003, roč.~6, č.~11, s.~1395-1399. ISSN~1387-7003.

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