| MAREK, Jaromír, Z. TRÁVNÍČEK a P. KOPEL. Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate. Acta Crystallographica Section C: Crystal Structure. Chester, UK: International Union of Crystallography, 2003, C59, č. 11, s. m429-m431, 3 s. ISSN 0108-2701. |
Další formáty:
BibTeX
LaTeX
RIS
@article{489393,
author = {Marek, Jaromír and Trávníček, Z. and Kopel, P.},
article_location = {Chester, UK},
article_number = {11},
keywords = {manganese(II); thiodiglycolic acid; crystal structure},
language = {eng},
issn = {0108-2701},
journal = {Acta Crystallographica Section C: Crystal Structure},
title = {Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate},
volume = {C59},
year = {2003}
}
TY - JOUR
ID - 489393
AU - Marek, Jaromír - Trávníček, Z. - Kopel, P.
PY - 2003
TI - Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate
JF - Acta Crystallographica Section C: Crystal Structure
VL - C59
IS - 11
SP - m429-m431
EP - m429-m431
PB - International Union of Crystallography
SN - 01082701
KW - manganese(II)
KW - thiodiglycolic acid
KW - crystal structure
N2 - The title compound, [Mn(C12H8N2)2(H2O)2](C4H4O4S).[Mn(C4H4O4S)(C12H8N2)2].13H2O, contains one dianion of thiodiglycolic acid (tdga2-) and two independent manganese(II) moieties, viz. [Mn(phen)2(H2O)2]2+ and [Mn(tdga)(phen)2], where phen is 1,10-phenanthroline. The MnII atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) A] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) A]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)2(H2O)2]2+ ion, with OO distances of 2.606 (2) and 2.649 (2) A. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules.
ER -
MAREK, Jaromír, Z. TRÁVNÍČEK a P. KOPEL. Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate. \textit{Acta Crystallographica Section C: Crystal Structure}. Chester, UK: International Union of Crystallography, 2003, C59, č.~11, s.~m429-m431, 3 s. ISSN~0108-2701.
|
