Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate

MAREK, Jaromír, Z. TRÁVNÍČEK and P. KOPEL. Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate. Acta Crystallographica Section C: Crystal Structure. Chester, UK: International Union of Crystallography, 2003, C59, No 11, p. m429-m431, 3 pp. ISSN 0108-2701.

Basic information

• Original name: Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate
• Authors: MAREK, Jaromír (203 Czech Republic, guarantor), Z. TRÁVNÍČEK (203 Czech Republic) and P. KOPEL (203 Czech Republic).
• Edition: Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2003, 0108-2701.

Other information

• Original language: English
• Type of outcome: Article in a journal
• Field of Study: 10402 Inorganic and nuclear chemistry
• Country of publisher: United Kingdom of Great Britain and Northern Ireland
• Confidentiality degree: is not subject to a state or trade secret
• Impact factor: Impact factor: 0.828
• RIV identification code: RIV/00216224:14330/03:00008583
• Organization unit: Faculty of Informatics
• Keywords in English: manganese(II); thiodiglycolic acid; crystal structure
• Tags: Crystal Structure, manganese(II), thiodiglycolic acid

Abstract

The title compound, [Mn(C12H8N2)2(H2O)2](C4H4O4S).[Mn(C4H4O4S)(C12H8N2)2].13H2O, contains one dianion of thiodiglycolic acid (tdga2-) and two independent manganese(II) moieties, viz. [Mn(phen)2(H2O)2]2+ and [Mn(tdga)(phen)2], where phen is 1,10-phenanthroline. The MnII atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) A] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) A]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)2(H2O)2]2+ ion, with OO distances of 2.606 (2) and 2.649 (2) A. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules.

Links

• GA203/02/0436, research and development project: Name: Aplikace krystalografických databází ve vědecké praxi
• MSM 143100008, plan (intention): Name: Genomy a jejich funkce

Investor: Ministry of Education, Youth and Sports of the CR, Genomes and their functions