TARABA, Jan and Zdirad ŽÁK. Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-. INORGANIC CHEMISTRY. 2003, vol. 2003, No 42, p. 3591-4, 4 pp. ISSN 0020-1669.
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Basic information
Original name Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-
Authors TARABA, Jan (203 Czech Republic) and Zdirad ŽÁK (203 Czech Republic, guarantor).
Edition INORGANIC CHEMISTRY, 2003, 0020-1669.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Czech Republic
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 3.389
RIV identification code RIV/00216224:14310/03:00009532
Organization unit Faculty of Science
Keywords in English ionic form of PPh2Cl3; trichloride ion; single-crystal X-ray analysis; 31P; 1H; and 35Cl-NMR; Raman spectra
Tags 1H, 31P, and 35Cl-NMR, ionic form of PPh2Cl3, Raman spectra, single-crystal X-ray analysis, trichloride ion
Changed by Changed by: RNDr. Jan Taraba, Ph.D., učo 10083. Changed: 20/5/2004 10:13.
Abstract
An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh2Cl3 with excess chlorine. The identity of this species was established by single-crystal X-ray analysis, 31P, 1H, and 35Cl-NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by 31P-NMR spectra and single-crystal X-ray analysis.
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MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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