SLUKA, Radek, Marek NEČAS and Pavel ŠINDELÁŘ. Dichlorotetrakis(tetrahydrofuran)aluminium trichloroethylaluminate. Acta Crystallographica Section E: Structure Reports Online. Blackwell Munksgaard, 2004, vol. 60, No 4, p. m447-m448, 2 pp. ISSN 1600-5368.
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Basic information
Original name Dichlorotetrakis(tetrahydrofuran)aluminium trichloroethylaluminate
Name in Czech Ethyl-trichlorohlinitan tetrakis(tetrahydrofuran)dichlorohlinitý
Authors SLUKA, Radek (203 Czech Republic), Marek NEČAS (203 Czech Republic, guarantor) and Pavel ŠINDELÁŘ (203 Czech Republic).
Edition Acta Crystallographica Section E: Structure Reports Online, Blackwell Munksgaard, 2004, 1600-5368.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Denmark
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.491
RIV identification code RIV/00216224:14310/04:00010017
Organization unit Faculty of Science
UT WoS 000220563800044
Keywords in English ALUMINUM TRICHLORIDE; TETRAHYDROFURAN; CRYSTAL; COMPLEXES
Tags ALUMINUM TRICHLORIDE, Complexes, CRYSTAL, TETRAHYDROFURAN
Changed by Changed by: doc. Mgr. Marek Nečas, Ph.D., učo 18809. Changed: 25/6/2009 11:47.
Abstract
The title compound, [AlCl2(C4H8O)(4)][AlCl3(C2H5)], was prepared by the unsymmetrical cleavage reaction of the EtAlCl2 dimer with tetrahydrofuran (THF). The [AlCl2(THF)(4)](+) cation forms an approximately regular octahedron, and the [AlCl3Et](-) anion is tetrahedral.
Abstract (in Czech)
[AlCl2(C4H8O)4][AlCl3(C2H5)] byl připraven nesymetrickým štěpením dimerního EtAlCl2 s tetrahydrofuranem (THF). Tetrakis(tetrahydrofuran)dichlorohlinitý kation má tvar pravidelného oktaedru a ethyl-trichlorohlinitanový anion je tetraedrický.
Links
GA203/02/0436, research and development projectName: Aplikace krystalografických databází ve vědecké praxi
GA203/04/0296, research and development projectName: Sonochemická syntéza oxidových a fosfátových materiálů
Investor: Czech Science Foundation, Sonochemical Synthesis of Oxide and Phosphate Materials
MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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