J 2004

Polysulfonylamines. Bis-(methylsulfonamido) Sulfone, bis-(trifluoromethylsulfonamido) Sulfone, its Synthesis and Crystal Structure.

TARABA, Jan and Zdirad ŽÁK

Basic information

Original name

Polysulfonylamines. Bis-(methylsulfonamido) Sulfone, bis-(trifluoromethylsulfonamido) Sulfone, its Synthesis and Crystal Structure.

Name in Czech

Polysolfonamidy. Bis(methylsulfonamido) sulfon, Bis(trifluormethylsulfonamido) sulfon, synthéza a krystalová struktura

Authors

TARABA, Jan (203 Czech Republic, guarantor) and Zdirad ŽÁK (203 Czech Republic)

Edition

Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2004, 0108-2701

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.728

RIV identification code

RIV/00216224:14310/04:00021207

Organization unit

Faculty of Science

Keywords in English

Polysulfonylamines; molecular structure; crystal structure
Změněno: 25/6/2006 09:14, RNDr. Jan Taraba, Ph.D.

Abstract

V originále

Bis(methylsulfamido) sulfone, SO2(NHSO2CH3)2 (1) is synthesized from imido-bis(sulfonylchloride) HN(SO2Cl)2 and bis(trimethylsilyl) methane CH2(Si(CH3)3)2 in trimethylchlorsilane solution. In the solid state there are two independent molecules linked by two N-H....O hydrogen bridges into infinite chains parallel to the b-axis. Bis(trifluoromethylsulfamido)sulfone, SO2(NHSO2CF3)2 (2) is formed by the reaction of trichlorophosphazo-sulfuryl trifuoromethane Cl3PNSO2CF3 with fluorosulfonic acid FSO3H. The molecules are bonded by bifurcated N-H....O bridges into infinite layers parallel to the [001] plane.

In Czech

Polysolfonamidy. Bis(methylsulfonamido) sulfon, Bis(trifluormethylsulfonamido) sulfon, synthéza a krystalová struktura

Links

MSM 143100011, plan (intention)
Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles