AHMED, M., P. SCHWENDT, M. SIVÁK and Jaromír MAREK. Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]. Transition Metal Chemistry. Netherlands: Kluwer Academic Publishers, 2004, vol. 29, No 6, p. 675-680. ISSN 0340-4285.
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Basic information
Original name Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]
Name in Czech Syntéza a charakterizace vanadičného komplexu s kyselinou alpha-hydroxyhippuriktovou . Krystalová struktura (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)].
Authors AHMED, M. (818 Egypt), P. SCHWENDT (703 Slovakia), M. SIVÁK (703 Slovakia) and Jaromír MAREK (203 Czech Republic, guarantor).
Edition Transition Metal Chemistry, Netherlands, Kluwer Academic Publishers, 2004, 0340-4285.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Netherlands
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.857
RIV identification code RIV/00216224:14310/04:00010671
Organization unit Faculty of Science
UT WoS 000225300200018
Keywords in English Peroxovanadium(V); X-ray structure; NMR; hydroxyhippuric acid
Tags hydroxyhippuric acid, NMR, Peroxovanadium(V), X-RAY STRUCTURE
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 10/2/2005 17:15.
Abstract
Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O, [M=K+(1), NH4+(2), NEt4+(3), NBu4+(4); n=5.5, 3, 8, 5) have been prepared and characterized by elemental analysis, i.r., u.v.-vis. and 51V-n.m.r. spectroscopies and by thermal analysis. The X-ray structure determination of (4) revealed the presence of dinuclear [V2O2(O2)2(R-alpha-hhip)(S-alpha-hhip)]2- anions with a planar V2O2 bridging core and seven-coordinated central atoms. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.
Abstract (in Czech)
Peroxovanadičnatý komplex s s kyselinou alpha-hydroxyhippuriktovou byl připraven a charakterizován elemental analýzou, IR , UV-VIS a 51V-NMR spektroskopickými technikami, termál. analýzou a RTG difrakcí.
Links
MSM 143100008, plan (intention)Name: Genomy a jejich funkce
Investor: Ministry of Education, Youth and Sports of the CR, Genomes and their functions
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