Synthesis and characterization of vanadium(V) complexes with
alpha-hydroxyhippuric acid. The X-ray crystal structure of
(NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip =
alpha-hydroxyhippurato(2-)]

J 2004

Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]

AHMED, M., P. SCHWENDT, M. SIVÁK a Jaromír MAREK

Základní údaje

Originální název

Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]

Název česky

Syntéza a charakterizace vanadičného komplexu s kyselinou alpha-hydroxyhippuriktovou . Krystalová struktura (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)].

Autoři

AHMED, M. (818 Egypt), P. SCHWENDT (703 Slovensko), M. SIVÁK (703 Slovensko) a Jaromír MAREK (203 Česká republika, garant)

Vydání

Transition Metal Chemistry, Netherlands, Kluwer Academic Publishers, 2004, 0340-4285

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.857

Kód RIV

RIV/00216224:14310/04:00010671

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000225300200018

Klíčová slova anglicky

Peroxovanadium(V); X-ray structure; NMR; hydroxyhippuric acid

Štítky

hydroxyhippuric acid, NMR, Peroxovanadium(V), X-RAY STRUCTURE

Změněno: 10. 2. 2005 17:15, doc. RNDr. Jaromír Marek, Ph.D.

Anotace

ORIG CZ

V originále

Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O, [M=K+(1), NH4+(2), NEt4+(3), NBu4+(4); n=5.5, 3, 8, 5) have been prepared and characterized by elemental analysis, i.r., u.v.-vis. and 51V-n.m.r. spectroscopies and by thermal analysis. The X-ray structure determination of (4) revealed the presence of dinuclear [V2O2(O2)2(R-alpha-hhip)(S-alpha-hhip)]2- anions with a planar V2O2 bridging core and seven-coordinated central atoms. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.

Česky

Peroxovanadičnatý komplex s s kyselinou alpha-hydroxyhippuriktovou byl připraven a charakterizován elemental analýzou, IR , UV-VIS a 51V-NMR spektroskopickými technikami, termál. analýzou a RTG difrakcí.

Návaznosti

MSM 143100008, záměr

Název: Genomy a jejich funkce

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Genomy a jejich funkce

Citovat

AHMED, M., P. SCHWENDT, M. SIVÁK a Jaromír MAREK. Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]. Transition Metal Chemistry. Netherlands: Kluwer Academic Publishers, 2004, roč. 29, č. 6, s. 675-680. ISSN 0340-4285.

@article{562524,
   author = {Ahmed, M. and Schwendt, P. and Sivák, M. and Marek, Jaromír},
   article_location = {Netherlands},
   article_number = {6},
   keywords = {Peroxovanadium(V); X-ray structure; NMR; hydroxyhippuric acid},
   language = {eng},
   issn = {0340-4285},
   journal = {Transition Metal Chemistry},
   title = {Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]},
   volume = {29},
   year = {2004}
}

TY  - JOUR
ID  - 562524
AU  - Ahmed, M. - Schwendt, P. - Sivák, M. - Marek, Jaromír
PY  - 2004
TI  - Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]
JF  - Transition Metal Chemistry
VL  - 29
IS  - 6
SP  - 675-680
EP  - 675-680
PB  - Kluwer Academic Publishers
SN  - 03404285
KW  - Peroxovanadium(V)
KW  - X-ray structure
KW  - NMR
KW  - hydroxyhippuric acid
N2  - Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O, [M=K+(1), NH4+(2), NEt4+(3), NBu4+(4); n=5.5, 3, 8, 5) have been prepared and characterized by elemental analysis, i.r., u.v.-vis. and 51V-n.m.r. spectroscopies and by thermal analysis. The X-ray structure determination of (4) revealed the presence of dinuclear [V2O2(O2)2(R-alpha-hhip)(S-alpha-hhip)]2- anions with a planar V2O2 bridging core and seven-coordinated central atoms. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.
ER  -

AHMED, M., P. SCHWENDT, M. SIVÁK a Jaromír MAREK. Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]. \textit{Transition Metal Chemistry}. Netherlands: Kluwer Academic Publishers, 2004, roč.~29, č.~6, s.~675-680. ISSN~0340-4285.

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