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@article{569260,
author = {Spíchal, Zdeněk and Nečas, Marek and Pinkas, Jiří},
article_location = {Spojené státy americké},
article_number = {6},
keywords = {Lanthanides Coordination Polymers},
language = {eng},
issn = {0020-1669},
journal = {INORGANIC CHEMISTRY},
title = {From Parquets to Bricks: A Series of Lanthanide Coordination Polymers with Bis(diphenylphosphino)ethane Dioxide},
volume = {44},
year = {2005}
}
TY - JOUR
ID - 569260
AU - Spíchal, Zdeněk - Nečas, Marek - Pinkas, Jiří
PY - 2005
TI - From Parquets to Bricks: A Series of Lanthanide Coordination Polymers with Bis(diphenylphosphino)ethane Dioxide
JF - INORGANIC CHEMISTRY
VL - 44
IS - 6
SP - 2074 - 2080
EP - 2074 - 2080
PB - American Chemical Society, Washington DC
SN - 00201669
KW - Lanthanides Coordination Polymers
N2 - A series of new layered coordination polymers consisting of Ln[Ph2P(O)-CH2CH2-P(O)Ph2]1.5 monomeric units, where Ln ) Pr(NO3)3, Nd(NO3)3, NdCl3, Sm(NO3)3, GdCl3, Dy(NO3)3, were synthesized and structurally characterized. The majority of prepared compounds display approximately rectangular building blocks. However, the adopted architecture strongly depends on additional nonbridging ligands in the coordination sphere of the cation, as well as on the reaction conditions and the employed solvent. Accordingly, the solvothermally prepared polymers exhibit either parquet-floor or brick-wall architecture, whereas the polymers from gel-diffusion reactions resemble honeycomb networks. The solvothermal reaction of the smallest lanthanide cation Lu3+ with Ph2P(O)-CH2CH2-P(O)Ph2 led to a molecular compound instead of a polymer.
ER -
SPÍCHAL, Zdeněk, Marek NEČAS a Jiří PINKAS. From Parquets to Bricks: A Series of Lanthanide Coordination Polymers with Bis(diphenylphosphino)ethane Dioxide. \textit{INORGANIC CHEMISTRY}. Spojené státy americké: American Chemical Society, Washington DC, 2005, roč.~44, č.~6, s.~2074 - 2080, 12 s. ISSN~0020-1669.
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