TÁBORSKÝ, Petr, Ivona SVOBODOVÁ, Zbigniew HNATEJKO, Premysl LUBAL, Stefan LIS, Michaela FÖRSTEROVÁ, Petr HERMANN, Ivan LUKEŠ and Josef HAVEL. Spectroscopic Characterization of Eu(III) Complexes with New Monophosphorus Acid Derivatives of H4dota. Journal of fluorescence. 2005, vol. 15, No 4, p. 507-512. ISSN 1053-0509. |
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@article{596827, author = {Táborský, Petr and Svobodová, Ivona and Hnatejko, Zbigniew and Lubal, Premysl and Lis, Stefan and Försterová, Michaela and Hermann, Petr and Lukeš, Ivan and Havel, Josef}, article_number = {4}, keywords = {Macrocyclic DOTA-like ligands; phosphonate and phosphinate Eu(III) complexes; hydration}, language = {eng}, issn = {1053-0509}, journal = {Journal of fluorescence}, title = {Spectroscopic Characterization of Eu(III) Complexes with New Monophosphorus Acid Derivatives of H4dota}, volume = {15}, year = {2005} }
TY - JOUR ID - 596827 AU - Táborský, Petr - Svobodová, Ivona - Hnatejko, Zbigniew - Lubal, Premysl - Lis, Stefan - Försterová, Michaela - Hermann, Petr - Lukeš, Ivan - Havel, Josef PY - 2005 TI - Spectroscopic Characterization of Eu(III) Complexes with New Monophosphorus Acid Derivatives of H4dota JF - Journal of fluorescence VL - 15 IS - 4 SP - 507-512 EP - 507-512 SN - 10530509 KW - Macrocyclic DOTA-like ligands KW - phosphonate and phosphinate Eu(III) complexes KW - hydration N2 - The luminescence lifetimes of europium(III) complexes with new monophosphorus acid derivatives of H4dota were measured by means of time-resolved laser-induced luminescence spectroscopy in H2O and D2O. The hydration numbers of these complexes were estimated using different empirical equations [Horrocks and Sudnick (1979) J. Am. Chem. Soc. 101 (1979) 334; Choppin and Barthelemy(1989) Inorg. Chem. 28, 33543357; Choppin and Bunzli Lanthanide probes in life, chemical and earth sciences. Theory and practice (1989); Kimura and Kato J. Alloys Comp. 275277 (1998) 806; Parker (1999) J. Chem. Soc., Perkin Trans. 2, 493503; Supkowski and Horroks (2002) Inorg. Chim. Acta. 340, 4448]. It was shown that all the relationships gave similar results with a satisfactory precision. The hydration numbers of complexes of H3do3a and H4dota agreed with the literature values. One water molecule is coordinated in complexes of the new ligands. ER -
TÁBORSKÝ, Petr, Ivona SVOBODOVÁ, Zbigniew HNATEJKO, Premysl LUBAL, Stefan LIS, Michaela FÖRSTEROVÁ, Petr HERMANN, Ivan LUKEŠ and Josef HAVEL. Spectroscopic Characterization of Eu(III) Complexes with New Monophosphorus Acid Derivatives of H4dota. \textit{Journal of fluorescence}. 2005, vol.~15, No~4, p.~507-512. ISSN~1053-0509.
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