Application of elimination voltammetry with linear scan to the
study of electrode processes on a graphite electrode

D 2006

Application of elimination voltammetry with linear scan to the study of electrode processes on a graphite electrode

ROZIK, Roland, Libuše TRNKOVÁ, Lenka ZERZÁNKOVÁ, Magdaléna STREČKOVÁ, Renáta ORIŇÁKOVÁ et. al.

Basic information

Original name

Application of elimination voltammetry with linear scan to the study of electrode processes on a graphite electrode

Name in Czech

Aplikace eleiminační voltametrie s lineárním skenem pro studium elektrodových prosesů na grafitové elektrodě

Authors

ROZIK, Roland (703 Slovakia), Libuše TRNKOVÁ (203 Czech Republic, guarantor), Lenka ZERZÁNKOVÁ (203 Czech Republic), Magdaléna STREČKOVÁ (703 Slovakia), Renáta ORIŇÁKOVÁ (703 Slovakia) and Miriam GÁLOVÁ (703 Slovakia)

Edition

Brno, Sborník příspěvků VI. Pracovního setkání fyzikálních chemiků a elektrochemiků, p. 96-97, 125 pp. 2006

Publisher

Masarykova universita

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10405 Electrochemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

RIV identification code

RIV/00216224:14310/06:00016638

Organization unit

Faculty of Science

ISBN

80-210-3943-4

Keywords in English

elimination voltammetry with linear scan; electrode processes; graphite electrode

Abstract

ORIG CZ

V originále

Introduction The solid electrodes in general, and the carbon materials (powder, fiber or glassy carbon) in particular, have been used widely in electroanalytical research and technological applications (functional or structural fuel cell components). Carbon materials have played an important role in solid electrode development for the following reasons. First, various forms are available at reasonable price. Second, the slow kinetics of carbon oxidation leads to a wide useful potential range. The carbon electrode can be modified by applying a thin metallic or polymer layer, or in case of the paste electrode by some additives or powders (graphite composite electrode) that increase the selectivity [1]. This contribution describes the voltammetric results of some depolarizers on a paraffin impregnated graphite electrode (PIGE). The graphite rod of spectral purity is a porous material and, therefore, must be impregnated with paraffin to fill the pores and decrease the background current [2]. The disadvantages of PIGE and/or all solid electrodes lie in the necessity of their mechanical regeneration and electrical activation of the surface. In this contribution we have focused on the interpretation of electrochemical processes (Cd2+/Cd, Ni2+/Ni, Cu2+/Cu) on PIGE in various solutions (Cl-, SO42-, NO3-, H3BO3) by using voltammetric methods (CV, LSV) including elimination voltammetry with linear scan (EVLS). The elimination procedure is based on the fact that the total voltammetric current responses recorded consist of a set of particular currents, e.g. charging, diffusion, and kinetic currents. The EVLS enables selected particular currents to be eliminated and unknown processes to be revealed [3-6]. Conclusion The graphite electrode (PIGE) is suitable for the study of reduction processes of metals (Cd, Cu, Ni) using voltammetric methods (CV, LSV). During deposition processes the elimination voltammetry (E4 function) revealed the Ipp peak. This peak reflects certain surface reaction controlled by kinetic (e.g. sorption, surface diffusion, nucleation).

In Czech

Aplikace eleiminační voltametrie s lineárním skenem pro studium elektrodových prosesů na grafitové elektrodě

Links

MSM0021622412, plan (intention)

Name: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Acronym: INCHEMBIOL)

Investor: Ministry of Education, Youth and Sports of the CR, Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL)

Citovat

ROZIK, Roland, Libuše TRNKOVÁ, Lenka ZERZÁNKOVÁ, Magdaléna STREČKOVÁ, Renáta ORIŇÁKOVÁ and Miriam GÁLOVÁ. Application of elimination voltammetry with linear scan to the study of electrode processes on a graphite electrode. In Sborník příspěvků VI. Pracovního setkání fyzikálních chemiků a elektrochemiků. Brno: Masarykova universita, 2006, p. 96-97, 125 pp. ISBN 80-210-3943-4.

@inproceedings{624644,
   author = {Rozik, Roland and Trnková, Libuše and Zerzánková, Lenka and Strečková, Magdaléna and Oriňáková, Renáta and Gálová, Miriam},
   address = {Brno},
   booktitle = {Sborník příspěvků VI. Pracovního setkání fyzikálních chemiků a elektrochemiků},
   keywords = {elimination voltammetry with linear scan; electrode processes; graphite electrode},
   language = {eng},
   location = {Brno},
   isbn = {80-210-3943-4},
   pages = {96-97},
   publisher = {Masarykova universita},
   title = {Application of elimination voltammetry with linear scan to the study of electrode processes on a graphite electrode},
   year = {2006}
}

TY  - JOUR
ID  - 624644
AU  - Rozik, Roland - Trnková, Libuše - Zerzánková, Lenka - Strečková, Magdaléna - Oriňáková, Renáta - Gálová, Miriam
PY  - 2006
TI  - Application of elimination voltammetry with linear scan to the study of electrode processes on a graphite electrode
PB  - Masarykova universita
CY  - Brno
SN  - 8021039434
KW  - elimination voltammetry with linear scan
KW  - electrode processes
KW  - graphite electrode
N2  - Introduction The solid electrodes in general, and the carbon materials (powder, fiber or glassy carbon) in particular, have been used widely in electroanalytical research and technological applications (functional or structural fuel cell components). Carbon materials have played an important role in solid electrode development for the following reasons. First, various forms are available at reasonable price. Second, the slow kinetics of carbon oxidation leads to a wide useful potential range. The carbon electrode can be modified by applying a thin metallic or polymer layer, or in case of the paste electrode by some additives or powders (graphite composite electrode) that increase the selectivity [1]. This contribution describes the voltammetric results of some depolarizers on a paraffin impregnated graphite electrode (PIGE). The graphite rod of spectral purity is a porous material and, therefore, must be impregnated with paraffin to fill the pores and decrease the background current [2]. The disadvantages of PIGE and/or all solid electrodes lie in the necessity of their mechanical regeneration and electrical activation of the surface. In this contribution we have focused on the interpretation of electrochemical processes (Cd2+/Cd, Ni2+/Ni, Cu2+/Cu) on PIGE in various solutions (Cl-, SO42-, NO3-, H3BO3) by using voltammetric methods (CV, LSV) including elimination voltammetry with linear scan (EVLS). The elimination procedure is based on the fact that the total voltammetric current responses recorded consist of a set of particular currents, e.g. charging, diffusion, and kinetic currents. The EVLS enables selected particular currents to be eliminated and unknown processes to be revealed [3-6]. Conclusion The graphite electrode (PIGE) is suitable for the study of reduction processes of metals (Cd, Cu, Ni) using voltammetric methods (CV, LSV). During deposition processes the elimination voltammetry (E4 function) revealed the Ipp peak. This peak reflects certain surface reaction controlled by kinetic (e.g. sorption, surface diffusion, nucleation).
ER  -

ROZIK, Roland, Libuše TRNKOVÁ, Lenka ZERZÁNKOVÁ, Magdaléna STREČKOVÁ, Renáta ORIŇÁKOVÁ and Miriam GÁLOVÁ. Application of elimination voltammetry with linear scan to the study of electrode processes on a graphite electrode. In \textit{Sborník příspěvků VI. Pracovního setkání fyzikálních chemiků a elektrochemiků}. Brno: Masarykova universita, 2006, p.~96-97, 125 pp. ISBN~80-210-3943-4.

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