Detailed Information on Publication Record
2006
A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2].
TARABA, Jan and Zdirad ŽÁKBasic information
Original name
A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2].
Name in Czech
Nový kation [N(SO2NMe3)2]+, jeho piprava a struktura. Dichlorid imidobis(sirové) kyseliny HN(SO2Cl)2. ást 1. Krystalové strktury KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 a [PCl4][N(SO2Cl)2].
Authors
TARABA, Jan (203 Czech Republic, guarantor) and Zdirad ŽÁK (203 Czech Republic)
Edition
INORGANIC CHEMISTRY, Spojené státy americké, American Chemical Society, Washington DC, 2006, 0020-1669
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Czech Republic
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 3.911
RIV identification code
RIV/00216224:14330/06:00015666
Organization unit
Faculty of Informatics
UT WoS
000237165500032
Keywords in English
Novel Cation; Synthesis; Imido-bis(sulfuric) Acid; Crystal Structures
Změněno: 6/7/2007 12:25, RNDr. JUDr. Vladimír Šmíd, CSc.
V originále
Several salts of bis(chlorosulfonyl)imide HN(SO2Cl)2 (1), namely two solvates of its potassium salt, KN(SO2Cl)2 1/2 CH3CN (1K1), KN(SO2Cl)2 1/6 CH2Cl2 (1K2), and tetrachlorophosphonium salt, [PCl4][N(SO2Cl)2] (2), were prepared and structurally characterized. The reaction of HN(SO2Cl)2 with Me3N gives the [N(SO2Cl)2]- salt of a novel cation, [N(SO2NMe3)2]+ .This cation is analogous to the [HC(SO2NMe3)2]+ cation but, in contrast to the latter, it is fairly stable to hydrolysis. The salt [N(SO2NMe3)2]+ [N(SO2Cl)2]- (3) can be converted into salts of other anions by its treatment with diluted aqueous solutions of the respective acids, and thus NO3-, Cl-.H2O, SeO32-, CH3COO-, HSO4-, (COO)22- salts were prepared. Treatment of 3 with concentrated HNO3 gave the [N(SO2NMe3)2]+ [O2NO-H-ONO2]- salt, and the addition of an HCl acidified FeCl3 aqueous solution yielded the FeCl4- salt. Methanolysis resulted in the formation of MeOSO3- and [MeOSO2NSO2OMe]- salts. All salts have been characterized by chemical analysis, vibrational spectroscopy, and X-ray structure determinations.
In Czech
V publikaci jsou uvedeny a prehlednym zpusobem shrnuty vysledky studia reaktivity dichloridu imidobis(sirove) kyseliny a jeho derivát. Souasti prace je rovnez charakterizace produktu studovanych reakcí vetn rtg. strukturní analýzy.
Links
| GP203/05/P104, research and development project |
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| MSM 143100011, plan (intention) |
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