Aluminophosphonates and phosphates by Nonhydrolytic Synthetic
Routes

D 2004

Aluminophosphonates and phosphates by Nonhydrolytic Synthetic Routes

PINKAS, Jiří, Jan KRATOCHVÍL, Zdeněk MORAVEC, Vendula REICHLOVÁ, Herbert W. ROESKY et. al.

Základní údaje

Originální název

Aluminophosphonates and phosphates by Nonhydrolytic Synthetic Routes

Název česky

Hlinitofosfonáty a fosfáty připravené nehydrolytickými syntetickými metodami

Autoři

PINKAS, Jiří (203 Česká republika, garant), Jan KRATOCHVÍL (203 Česká republika), Zdeněk MORAVEC (203 Česká republika), Vendula REICHLOVÁ (203 Česká republika) a Herbert W. ROESKY (276 Německo)

Vydání

1. vyd. London, Materials Discussion 7 - P31, od s. 31-31, 1 s. 2004

Nakladatel

Materials Chemistry Forum, Dalton Division

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/04:00024567

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Aluminophosphonates; Nonhydrolytic; Synthesis

Štítky

aluminophosphonates, nonhydrolytic, synthesis

Příznaky

Mezinárodní význam

Změněno: 31. 5. 2009 22:21, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

ORIG CZ

V originále

Aluminophosphonates and phosphates possess two and threedimensional structures related to zeolitic materials. New synthetic methods for their preparation are currently intensively studied with the aim of extending the number of structural types and chemical compositions. The majority of the procedures is based on aqueous chemistry. The aim of our studies is to synthesize aluminophosphonates and phosphates by several different nonhydrolytic routes. In one approach we prepared molecular building blocks, such as 4R and D4R, from metal alkyls, alkoxides, halides and amides, and phosphoric, phosphonic and phosphinic acids and their esters. Several new derivatives were characterized by spectroscopic and structural methods and we studied their chemical reactivity in substitution reactions at the vertices of these polygonal and polyhedral molecules. The other emphasis of our work is on finding suitable solution or thermal methods to convert these molecular precursors to solid materials. In this direction, nonhydrolytic reactions of the 4R derivatives with Lewis acids and bases were studied to obtain aluminophosphate materials with extended frameworks. Sonochemically activated reactions of aluminum precursors, such as triisopropoxide and tris(acetylacetonate), in inert (tetraglyme) and reactive (tributyl phosphate) solvents were found to provide oxidic and phosphate materials, respectively.

Česky

Hlinitofosfonáty a fosfáty připravené nehydrolytickými syntetickými metodami

Návaznosti

GA203/04/0296, projekt VaV

Název: Sonochemická syntéza oxidových a fosfátových materiálů

Investor: Grantová agentura ČR, Sonochemická syntéza oxidových a fosfátových materiálů

Citovat

PINKAS, Jiří, Jan KRATOCHVÍL, Zdeněk MORAVEC, Vendula REICHLOVÁ a Herbert W. ROESKY. Aluminophosphonates and phosphates by Nonhydrolytic Synthetic Routes. In Materials Discussion 7 - P31. 1. vyd. London: Materials Chemistry Forum, Dalton Division, 2004, s. 31-31.

@inproceedings{711033,
   author = {Pinkas, Jiří and Kratochvíl, Jan and Moravec, Zdeněk and Reichlová, Vendula and Roesky, Herbert W.},
   address = {London},
   booktitle = {Materials Discussion 7 - P31},
   edition = {1.},
   keywords = {Aluminophosphonates; Nonhydrolytic; Synthesis},
   language = {eng},
   location = {London},
   pages = {31-31},
   publisher = {Materials Chemistry Forum, Dalton Division},
   title = {Aluminophosphonates and phosphates by Nonhydrolytic Synthetic Routes},
   year = {2004}
}

TY  - JOUR
ID  - 711033
AU  - Pinkas, Jiří - Kratochvíl, Jan - Moravec, Zdeněk - Reichlová, Vendula - Roesky, Herbert W.
PY  - 2004
TI  - Aluminophosphonates and phosphates by Nonhydrolytic Synthetic Routes
PB  - Materials Chemistry Forum, Dalton Division
CY  - London
KW  - Aluminophosphonates
KW  - Nonhydrolytic
KW  - Synthesis
N2  - Aluminophosphonates and phosphates possess two and threedimensional structures related to zeolitic materials. New synthetic methods for their preparation are currently intensively studied with the aim of extending the number of structural types and chemical compositions. The majority of the procedures is based on aqueous chemistry. The aim of our studies is to synthesize aluminophosphonates and phosphates by several different nonhydrolytic routes. In one approach we prepared molecular building blocks, such as 4R and D4R, from metal alkyls, alkoxides, halides and amides, and phosphoric, phosphonic and phosphinic acids and their esters. Several new derivatives were characterized by spectroscopic and structural methods and we studied their chemical reactivity in substitution reactions at the vertices of these polygonal and polyhedral molecules. The other emphasis of our work is on finding suitable solution or thermal methods to convert these molecular precursors to solid materials. In this direction, nonhydrolytic reactions of the 4R derivatives with Lewis acids and bases were studied to obtain aluminophosphate materials with extended frameworks. Sonochemically activated reactions of aluminum precursors, such as triisopropoxide and tris(acetylacetonate), in inert (tetraglyme) and reactive (tributyl phosphate) solvents were found to provide oxidic and phosphate materials, respectively.
ER  -

PINKAS, Jiří, Jan KRATOCHVÍL, Zdeněk MORAVEC, Vendula REICHLOVÁ a Herbert W. ROESKY. Aluminophosphonates and phosphates by Nonhydrolytic Synthetic Routes. In \textit{Materials Discussion 7 - P31}. 1. vyd. London: Materials Chemistry Forum, Dalton Division, 2004, s.~31-31.

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