2007
[mu]-Trithiocyanurato-[kappa]4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-[kappa]3N,N',N'')zinc(II)] perchlorate monohydrate
TRÁVNÍČEK, Zdeněk; Jaromír MAREK and Šárka ČERMÁKOVÁBasic information
Original name
[mu]-Trithiocyanurato-[kappa]4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-[kappa]3N,N',N'')zinc(II)] perchlorate monohydrate
Name in Czech
Monohydrát dvojjaderného pentamethyldiethylentriamino-zinečnatého komplexu s kyselinou trithiocyanurovou a chloristanovým iontem
Authors
TRÁVNÍČEK, Zdeněk (203 Czech Republic); Jaromír MAREK (203 Czech Republic, guarantor) and Šárka ČERMÁKOVÁ (203 Czech Republic)
Edition
Acta Crystallographica Section E, Structure Reports Online, 2007, 1600-5368
Other information
Language
English
Type of outcome
Article in a journal
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United Kingdom of Great Britain and Northern Ireland
Confidentiality degree
is not subject to a state or trade secret
Impact factor
Impact factor: 0.508
RIV identification code
RIV/00216224:14310/07:00021954
Organization unit
Faculty of Science
UT WoS
000245434500072
Keywords in English
Zinc(II); trithiocyanuric acid; structure;
Tags
Reviewed
Changed: 2/3/2007 17:01, doc. RNDr. Jaromír Marek, Ph.D.
In the original language
In the title compound, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, the dinuclear ZnII metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and an S and an N atom of ttc. The crystal structure is stabilized by O-H...O, O-H...S, C-H...S and C-H...O interactions connecting the cations, the ClO4- anions and the water molecules.
In Czech
V titulním dvojjaderném komplexu, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, jsou 2 centrální Zn(II) můstkově propojeny trithiocyanurovým trianionem (ttc). Každý z centrálních atomů zaujímá geometrii porušené trojboké bipyramidy a je navázán na 3 N atomy diethylenetriaminu a S a N atom ttc. Krystalová struktura je dále stabilizována nevazebnými interakcemi O-H...O, O-H...S, C-H...S a C-H...O spojujícími kationy, ClO4- aniony a molekuly vody.
Links
| MSM0021622415, plan (intention) |
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