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@article{717629, author = {Pazderski, Leszek and Toušek, Jaromír and Sitkowski, Jerzy and Kozerski, Lech and Marek, Radek and Szlyk, Edward}, article_number = {1}, doi = {http://dx.doi.org/10.1002/mrc.1910}, keywords = {quantum chemical NMR calculations}, language = {eng}, issn = {0749-1581}, journal = {Magnetic Resonance in Chemistry}, title = {1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline}, url = {http://dx.doi.org/10.1002/mrc.1910}, volume = {45}, year = {2007} }
TY - JOUR ID - 717629 AU - Pazderski, Leszek - Toušek, Jaromír - Sitkowski, Jerzy - Kozerski, Lech - Marek, Radek - Szlyk, Edward PY - 2007 TI - 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline JF - Magnetic Resonance in Chemistry VL - 45 IS - 1 SP - 24-36 EP - 24-36 PB - John Wiley & Sons, Ltd. SN - 07491581 KW - quantum chemical NMR calculations UR - http://dx.doi.org/10.1002/mrc.1910 L2 - http://dx.doi.org/10.1002/mrc.1910 N2 - Au(III), Co(III) and Rh(III) chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) of the general formulae [(MLCl3)-L-1], trans-[(ML4Cl2)-L-2](+), mer-[(ML3Cl3)-L-2], [M-1(LL)Cl-2](+), cis-[M-2(LL)(2)Cl-2](+), where M-1 = Au; M-2 = Co, Rh; L = py; LL = bpy, phen, were studied by H-1-C-13 HMBC and H-1-N-15 HMQC/HSQC. The H-1, C-13 and N-15 coordination shifts (the latter from ca -78 to ca -10 7 ppm) are discussed in relation to the type of metal, electron configuration, coordination sphere geometry and the type of ligand. The C-13 and N-15 chemical shifts were also calculated by quantum-chemical NMR methods, which reproduced well the experimental tendencies concerning the coordination sphere geometry and the ligand type. ER -
PAZDERSKI, Leszek, Jaromír TOUŠEK, Jerzy SITKOWSKI, Lech KOZERSKI, Radek MAREK and Edward SZLYK. 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline. \textit{Magnetic Resonance in Chemistry}. John Wiley \&{} Sons, Ltd., 2007, vol.~45, No~1, p.~24-36. ISSN~0749-1581. Available from: https://dx.doi.org/10.1002/mrc.1910.
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