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@article{724309,
author = {Dastychová, Lenka and Sotolářová, Marie and Dastych, Dalibor and Taraba, Jan and Nečas, Marek and Příhoda, Jiří},
article_number = {26},
keywords = {Chlorodithiophosphoric acid pyridiniumbetaine; Phosphorus pentasulfide; Diazaphosphetidine; Cyclic thiophosphates; Palladium(II) complex},
language = {eng},
issn = {0277-5387},
journal = {Polyhedron},
title = {Reactions of P4S10 and pyPS2Cl with N,N-diphenylurea and N,N-diphenylthiourea},
url = {http://www.elsevier.com/wps/find/journaldescription.cws_home/218/description#description},
volume = {2007},
year = {2007}
}
TY - JOUR
ID - 724309
AU - Dastychová, Lenka - Sotolářová, Marie - Dastych, Dalibor - Taraba, Jan - Nečas, Marek - Příhoda, Jiří
PY - 2007
TI - Reactions of P4S10 and pyPS2Cl with N,N-diphenylurea and N,N-diphenylthiourea
JF - Polyhedron
VL - 2007
IS - 26
SP - 4250-4256
EP - 4250-4256
SN - 02775387
KW - Chlorodithiophosphoric acid pyridiniumbetaine
KW - Phosphorus pentasulfide
KW - Diazaphosphetidine
KW - Cyclic thiophosphates
KW - Palladium(II) complex
UR - http://www.elsevier.com/wps/find/journaldescription.cws_home/218/description#description
N2 - The reaction of P4S10 (1) with N,N-diphenylurea (PhNH)2CO (2) results in new heterocyclic compounds containing the (PSN)2 cycle and the cyclic thiophosphates [pyH]2[P2S8] (5), [pyH]2[P2S7] (6) and [pyH]3[P3S9] (7). A similar reaction, but carried out with N,N -diphenylthiourea (PhNH)2CS (8), leads to the formation of 4 and 6. pyPS2Cl (9), used as an alternative starting material, also yields compounds 3, 4, 5, and further [pyH][PS2Cl2] (10) and S8 after reaction with 2. Compound 3 reacts with Pd(CH3COO)2, with the formation of the complex [Pd(Ph2N2COPS2)2] (11). The crystal structures of 3 and 7 were determined by single crystal X-ray diffraction.
ER -
DASTYCHOVÁ, Lenka, Marie SOTOLÁŘOVÁ, Dalibor DASTYCH, Jan TARABA, Marek NEČAS a Jiří PŘÍHODA. Reactions of P4S10 and pyPS2Cl with N,N-diphenylurea and N,N-diphenylthiourea. \textit{Polyhedron}. 2007, roč.~2007, č.~26, s.~4250-4256. ISSN~0277-5387.
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