Detailed Information on Publication Record
2008
Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate
PEVEC, Andrej, Alojz DEMSAR, Jiří PINKAS and Marek NEČASBasic information
Original name
Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate
Name in Czech
Syntéza, spektroskopická a strukturní charakterizace nového molekulárního fosfonátu titaničitého
Authors
PEVEC, Andrej (705 Slovenia), Alojz DEMSAR (705 Slovenia), Jiří PINKAS (203 Czech Republic, guarantor) and Marek NEČAS (203 Czech Republic)
Edition
Inorganic Chemistry Communication, Amsterdam, Elsevier, 2008, 1387-7003
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Netherlands
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 1.854
RIV identification code
RIV/00216224:14310/08:00025750
Organization unit
Faculty of Science
UT WoS
000253105200002
Keywords in English
Titanium; Phosphonate; Crystal structure; Hydrogen bond
Tags
International impact, Reviewed
Změněno: 26/6/2009 16:31, prof. RNDr. Jiří Pinkas, Ph.D.
V originále
Dititanate [{Ti(C5Me4Et)(O2P(OH)Me)(O2P(O)Me)}2] (1) was prepared from (C5Me4Et)TiF3 and MeP(O)(OSiMe3)2. The molecular structure of the compound 1 has been determined by single-crystal X-ray diffraction analysis. In the cage cluster, two titanium atoms are bridged by two bidentate monoanionic and by two bidentate dianionic methylphosphonate groups. The OH groups of the monoanionic phosphonates and oxygen atoms of the dianionic phosphonates are connected by strong intramolecular hydrogen bonds. The NMR spectroscopy reveals the fast proton migration within the hydrogen bond.
In Czech
Syntéza, spektroskopická a strukturní charakterizace nového molekulárního fosfonátu titaničitého.
Links
| MSM0021622410, plan (intention) |
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