TRÁVNÍČEK, Z., Jaromír MAREK and Š. ČERMÁKOVÁ. (mu(3)-benzene-1,3,5-tricarboxylato)tris-[aqua(N,N,N ',N '',N ''-pentamethyldiethylenetriamine)nickel(II)]tris(perchlorate) 4.25-hydrate. Acta Crystallographica Section E: Structure Reports Online. Chester, England: IUCr, 2007, vol. 63, No 11, p. M2860-M2861, 2 pp. ISSN 1600-5368.
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Basic information
Original name (mu(3)-benzene-1,3,5-tricarboxylato)tris-[aqua(N,N,N ',N '',N ''-pentamethyldiethylenetriamine)nickel(II)]tris(perchlorate) 4.25-hydrate
Name in Czech (mu(3)-benzene-1,3,5-tricarboxylato)tris-[aqua(N,N,N ',N '',N ''-pentamethyldiethylenetriamine)nickel(II)]tris(perchlorate) 4.25-hydrate
Authors TRÁVNÍČEK, Z. (203 Czech Republic), Jaromír MAREK (203 Czech Republic, guarantor) and Š. ČERMÁKOVÁ (203 Czech Republic).
Edition Acta Crystallographica Section E: Structure Reports Online, Chester, England, IUCr, 2007, 1600-5368.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.508
RIV identification code RIV/00216224:14310/07:00033221
Organization unit Faculty of Science
UT WoS 000251281800186
Keywords in English COORDINATION POLYMERS; MAGNETIC PROPERTIES; CRYSTAL; BENZENETRICARBOXYLATE; COMPLEXES
Tags BENZENETRICARBOXYLATE, Complexes, Coordination polymers, CRYSTAL, magnetic properties
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 7/2/2008 14:48.
Abstract
In the title complex, [Ni-3(C9H3O6)(C9H23N3)(3)(H2O)(3)]-(ClO4)(3)center dot 4.25H(2)O, the three Ni-II centres are bridged by a benzene-1,3,5-tricarboxylate(3-) anion (btc). Each of the metal centres is coordinated by three N atoms of a tridentate N, N, N ', N '', N ''-pentamethyldiethylenetriamine ligand (pmdien), two O atoms of the btc ligand and one water molecule in a distorted octahedral geometry. The secondary structure is stabilized by a variety of O-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot O interactions that serve to connect the complex cations, perchlorate anions and water solvent molecules. Variability of intermolecular contacts stabilizing the crystal structure leads to disorder of part of O atoms of two perchlorate anions between two positions with occupancies 0.632 (5) and 0.337 (7).
Abstract (in Czech)
V článku je detailně popisována krystalová struktura titulního nikelnatého komplexu.
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MSM0021622410, plan (intention)Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures
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