J 2007

(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)

MAREK, Jaromír, Z. TRÁVNÍČEK and Š. ČERMÁKOVÁ

Basic information

Original name

(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)

Name in Czech

(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)

Authors

MAREK, Jaromír (203 Czech Republic, guarantor), Z. TRÁVNÍČEK (203 Czech Republic) and Š. ČERMÁKOVÁ (203 Czech Republic)

Edition

Acta Crystallographica Section E: Structure Reports Online, Chester, England, IUCr, 2007, 1600-5368

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.508

RIV identification code

RIV/00216224:14310/07:00023838

Organization unit

Faculty of Science

UT WoS

000248080100111

Keywords in English

CRYSTAL; PERCHLORATE

Tags

Reviewed
Změněno: 7/2/2008 15:00, doc. RNDr. Jaromír Marek, Ph.D.

Abstract

V originále

In the title compound, [ Zn-3( C3N3S3)(C9H23N3) 3]( ClO4) 3, the three Zn-II centres, related by the body-diagonal threefold symmetry along [ 111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded by three N atoms of a tridentate N, N, N', N", N"-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of non-bonding C-H . . O interactions, connecting the cation and perchlorate anions.

In Czech

V článku je detailně popisována krystalová struktura titulního zinečnatého komplexu.

Links

MSM0021622415, plan (intention)
Name: Molekulární podstata buněčných a tkáňových regulací
Investor: Ministry of Education, Youth and Sports of the CR, Molecular basis of cell and tissue regulations