Detailed Information on Publication Record
2007
(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)
MAREK, Jaromír, Z. TRÁVNÍČEK and Š. ČERMÁKOVÁBasic information
Original name
(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)
Name in Czech
(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)
Authors
MAREK, Jaromír (203 Czech Republic, guarantor), Z. TRÁVNÍČEK (203 Czech Republic) and Š. ČERMÁKOVÁ (203 Czech Republic)
Edition
Acta Crystallographica Section E: Structure Reports Online, Chester, England, IUCr, 2007, 1600-5368
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United Kingdom of Great Britain and Northern Ireland
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 0.508
RIV identification code
RIV/00216224:14310/07:00023838
Organization unit
Faculty of Science
UT WoS
000248080100111
Keywords in English
CRYSTAL; PERCHLORATE
Tags
Tags
Reviewed
Změněno: 7/2/2008 15:00, doc. RNDr. Jaromír Marek, Ph.D.
V originále
In the title compound, [ Zn-3( C3N3S3)(C9H23N3) 3]( ClO4) 3, the three Zn-II centres, related by the body-diagonal threefold symmetry along [ 111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded by three N atoms of a tridentate N, N, N', N", N"-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of non-bonding C-H . . O interactions, connecting the cation and perchlorate anions.
In Czech
V článku je detailně popisována krystalová struktura titulního zinečnatého komplexu.
Links
MSM0021622415, plan (intention) |
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