Detailed Information on Publication Record
2008
New nonaqueous methods for the preparation of oxide and phosphate materials
MORAVEC, Zdeněk, Marek NEČAS, Jiří PINKAS and Sanjay MATHURBasic information
Original name
New nonaqueous methods for the preparation of oxide and phosphate materials
Name in Czech
Nové bezvodé metody přípravy oxidických a fosfátových materiálů
Name (in English)
New nonaqueous methods for the preparation of oxide and phosphate materials
Authors
Edition
Bratislava, SK, VII. SEMINÁR Pokroky v anorganickej chémii, p. 52-53, 1 pp. 2008
Publisher
Univerzita Komenského v Bratislave
Other information
Language
Czech
Type of outcome
Stať ve sborníku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Slovakia
Confidentiality degree
není předmětem státního či obchodního tajemství
Organization unit
Faculty of Science
ISBN
978-80-223-2523-3
Keywords in English
aluminium chloro-alkoxides; lanthanide phosphates; CVD
Tags
International impact
Změněno: 7/5/2009 16:22, Mgr. Zdeněk Moravec, Ph.D.
V originále
Nonaqueos reactions of tris(dimethylamido)alane with phosphonic and phosphinic acids were tested. We examined the sterical and electronic influences of different organic substituents, such as Me, CCl3, Ph, tBu, on the molecular structure of the products. Second subject of our research was the reactions of dichloroethylalane with various alcohols, such as cyclohexanol, n-butanol, and phenol. The prepared aluminium alkoxides could be used as single source precursors for the preparation of aluminium oxide or as precursors to aluminium phosphates by chemical or thermal routes.
In English
Nonaqueos reactions of tris(dimethylamido)alane with phosphonic and phosphinic acids were tested. We examined the sterical and electronic influences of different organic substituents, such as Me, CCl3, Ph, tBu, on the molecular structure of the products. Second subject of our research was the reactions of dichloroethylalane with various alcohols, such as cyclohexanol, n-butanol, and phenol. The prepared aluminium alkoxides could be used as single source precursors for the preparation of aluminium oxide or as precursors to aluminium phosphates by chemical or thermal routes.
Links
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