2010
T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes
KALETA, Jiří, Josef MICHL a Ctibor MAZALZákladní údaje
Originální název
T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes
Název česky
Molekulární stavební bloky kombinací bridgehead a bridge substituce na bicyklo[1.1.1]pentanech
Autoři
KALETA, Jiří (203 Česká republika, domácí), Josef MICHL (840 Spojené státy) a Ctibor MAZAL (203 Česká republika, garant, domácí)
Vydání
Journal of Organic Chemistry, 2010, 0022-3263
Další údaje
Jazyk
angličtina
Typ výsledku
Článek v odborném periodiku
Obor
10401 Organic chemistry
Stát vydavatele
Spojené státy
Utajení
není předmětem státního či obchodního tajemství
Odkazy
Impakt faktor
Impact factor: 4.002
Kód RIV
RIV/00216224:14310/10:00051340
Organizační jednotka
Přírodovědecká fakulta
UT WoS
000275884400024
Klíčová slova česky
organic synthesis;bicyclopentanes;strained compounds;molecular building blocks
Klíčová slova anglicky
organic synthesis;bicyclopentanes;strained compounds;molecular building blocks
Příznaky
Mezinárodní význam, Recenzováno
Změněno: 23. 3. 2012 12:09, Mgr. Anísa Kabarová
V originále
Derivatives of bicyclo[1.1.1]pentane differentially substituted in bridgehead (1,3) and bridge (2,4) positions have been synthesized. They represent a new T-shaped structural module consisting of a rigid rod with a nearly freely rotating side arm, possibly useful as a molecular building block in syntheses of more complex covalent or supramolecular scaffolds useful in bottom-up construction of molecular level devices or materials. For good chemical connectivity in the axial direction, carboxylates, ethynyls, and acetylsulfanyl groups were installed at the bridgeheads. Quinoxalines were attached in the transverse direction through a highly reactive alpha-diketone system located at the bridges.
Česky
Derivatives of bicyclo[1.1.1]pentane differentially substituted in bridgehead (1,3) and bridge (2,4) positions have been synthesized. They represent a new T-shaped structural module consisting of a rigid rod with a nearly freely rotating side arm, possibly useful as a molecular building block in syntheses of more complex covalent or supramolecular scaffolds useful in bottom-up construction of molecular level devices or materials. For good chemical connectivity in the axial direction, carboxylates, ethynyls, and acetylsulfanyl groups were installed at the bridgeheads. Quinoxalines were attached in the transverse direction through a highly reactive alpha-diketone system located at the bridges.
Návaznosti
| ME09114, projekt VaV |
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