| BANERJEE, Ishita, Jaromír MAREK, Radovan HERCHEL a Mahammad ALI. Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies. Polyhedron. Velká Británie: Elsevier Science Ltd., 2010, roč. 29, č. 4, s. 1201-1208. ISSN 0277-5387. |
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@article{885666,
author = {Banerjee, Ishita and Marek, Jaromír and Herchel, Radovan and Ali, Mahammad},
article_location = {Velká Británie},
article_number = {4},
keywords = {EE and EO bridging; Synthesis; Crystal structures; Ferro and antiferromagnetic coupling},
language = {eng},
issn = {0277-5387},
journal = {Polyhedron},
title = {Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies},
url = {http://dx.doi.org/10.1016/j.poly.2009.12.023},
volume = {29},
year = {2010}
}
TY - JOUR
ID - 885666
AU - Banerjee, Ishita - Marek, Jaromír - Herchel, Radovan - Ali, Mahammad
PY - 2010
TI - Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies
JF - Polyhedron
VL - 29
IS - 4
SP - 1201-1208
EP - 1201-1208
PB - Elsevier Science Ltd.
SN - 02775387
KW - EE and EO bridging
KW - Synthesis
KW - Crystal structures
KW - Ferro and antiferromagnetic coupling
UR - http://dx.doi.org/10.1016/j.poly.2009.12.023
N2 - Four azide bridged dinuclear copper(II) complexes have been synthesized, out of which complexes 1 and 2 have been characterized structurally. In Complex 1 the two bridging azide ligands have connected the two metal centers in an end-on (EO) fashion with aSP (asymmetric Square Pyramidal) geometry and showed an weak antiferromagnetic interaction. On the contrary, in complex 2, the two metal centers have been connected in end-to-end (EE) fashion exhibiting moderately strong ferromagnetic interaction. Cyclic voltammetric studies performed on all the four complexes show a reasonably good correlations.
ER -
BANERJEE, Ishita, Jaromír MAREK, Radovan HERCHEL a Mahammad ALI. Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies. \textit{Polyhedron}. Velká Británie: Elsevier Science Ltd., 2010, roč.~29, č.~4, s.~1201-1208. ISSN~0277-5387.
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