Detailed Information on Publication Record
2010
Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies
BANERJEE, Ishita, Jaromír MAREK, Radovan HERCHEL and Mahammad ALIBasic information
Original name
Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies
Authors
BANERJEE, Ishita (356 India), Jaromír MAREK (203 Czech Republic, guarantor, belonging to the institution), Radovan HERCHEL (203 Czech Republic) and Mahammad ALI (356 India)
Edition
Polyhedron, Velká Británie, Elsevier Science Ltd. 2010, 0277-5387
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United Kingdom of Great Britain and Northern Ireland
Confidentiality degree
není předmětem státního či obchodního tajemství
References:
Impact factor
Impact factor: 2.034
RIV identification code
RIV/00216224:14310/10:00044020
Organization unit
Faculty of Science
UT WoS
000276000900002
Keywords (in Czech)
krystalová struktura; syntéza;
Keywords in English
EE and EO bridging; Synthesis; Crystal structures; Ferro and antiferromagnetic coupling
Tags
Reviewed
Změněno: 2/5/2011 15:47, doc. RNDr. Jaromír Marek, Ph.D.
Abstract
V originále
Four azide bridged dinuclear copper(II) complexes have been synthesized, out of which complexes 1 and 2 have been characterized structurally. In Complex 1 the two bridging azide ligands have connected the two metal centers in an end-on (EO) fashion with aSP (asymmetric Square Pyramidal) geometry and showed an weak antiferromagnetic interaction. On the contrary, in complex 2, the two metal centers have been connected in end-to-end (EE) fashion exhibiting moderately strong ferromagnetic interaction. Cyclic voltammetric studies performed on all the four complexes show a reasonably good correlations.
Links
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