D 2010

Vliv segregace nemagnetických nečistot na strukturu a vlastnosti hranic zrn v niklu

VŠIANSKÁ, Monika and Mojmír ŠOB

Basic information

Original name

Vliv segregace nemagnetických nečistot na strukturu a vlastnosti hranic zrn v niklu

Name in Czech

Vliv segregace nemagnetických nečistot na strukturu a vlastnosti hranic zrn v niklu

Name (in English)

The effect of segregated nonmagnetic impurities on the structure and properties of grain boundaries in nickel

Edition

Brno, Sborník doktorské konference: Víceúrovňový design pokrokových materiálů, p. 7-12, 6 pp. 2010

Publisher

Ústav fyziky materiálů AVČR

Other information

Language

Czech

Type of outcome

Proceedings paper

Field of Study

10403 Physical chemistry

Country of publisher

Czech Republic

Confidentiality degree

is not subject to a state or trade secret

Publication form

printed version "print"

RIV identification code

RIV/00216224:14310/10:00049673

Organization unit

Faculty of Science

ISBN

978-80-87434-02-4

Keywords (in Czech)

hranice zrn nikl segregace

Keywords in English

grain boundary segregation nickel

Tags

Changed: 5/2/2013 16:41, prof. RNDr. Mojmír Šob, DrSc.

Abstract

In the original language

We have studied segregation and embrittling energy of sp elements of the 3rd, 4th and 5th period (Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te) at the Sigma5(210) grain boundary (GB) in fcc nickel and the segregation of these impurities at the (210) free surface (FS). Full relaxation of the geometric configuration of the GB and FS without and with impurities has been performed and the effect of impurities on the distribution of magnetic moments has been analysed. We determined the embrittling energy from the difference between the GB and FS binding energies on the basis of the Rice Wang model. and we separated embrittling energy into the chemical and mechanical part.

In English

We have studied segregation and embrittling energy of sp elements of the 3rd, 4th and 5th period (Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te) at the Sigma5(210) grain boundary (GB) in fcc nickel and the segregation of these impurities at the (210) free surface (FS). Full relaxation of the geometric configuration of the GB and FS without and with impurities has been performed and the effect of impurities on the distribution of magnetic moments has been analysed. We determined the embrittling energy from the difference between the GB and FS binding energies on the basis of the Rice Wang model. and we separated embrittling energy into the chemical and mechanical part.

Links

GA202/09/1786, research and development project
Name: Teoretické studium hranic zrn s bodovými poruchami a jejich agregáty
Investor: Czech Science Foundation, Theoretical studies of grain boundaries with point defects and their aggregates
GD106/09/H035, research and development project
Name: Víceúrovňový design pokrokových materiálů
Investor: Czech Science Foundation
MSM0021622410, plan (intention)
Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures