Polymerisation and Surface Modification of Methacrylate
Monoliths in Polyimide Channels and Polyimide Coated
Capillaries using 660 nm Light Emitting Diodes

J 2011

Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes

WALSH, Zarah, Paul A. LEVKIN, Silvija ABELE, Silvia SCARMAGNANI, Dominik HEGER et. al.

Základní údaje

Originální název

Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes

Autoři

WALSH, Zarah (372 Irsko), Paul A. LEVKIN (840 Spojené státy), Silvija ABELE (372 Irsko), Silvia SCARMAGNANI (372 Irsko), Dominik HEGER (203 Česká republika, domácí), Petr KLÁN (203 Česká republika, domácí), Dermot DIAMOND (372 Irsko), Brett PAULL (372 Irsko), Frantisek SVEC (840 Spojené státy) a Miroslav MACKA (372 Irsko, garant, domácí)

Vydání

Journal of Chromatography A, Amsterdam, Elsevier, 2011, 0021-9673

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10401 Organic chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 4.531

Kód RIV

RIV/00216224:14310/11:00049770

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.chroma.2011.03.021

UT WoS

000291065500017

Klíčová slova anglicky

Monolith Photo-initiated polymerisation Visible light Red LED Polyimide Micro-fluidic chips Grafting

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 20. 4. 2012 10:20, Ing. Andrea Mikešková

Anotace

V originále

An investigation into the preparation of monolithic separation media utilising a cyanine dye sensitiser/triphenylbutylborate/N-methoxy-4-phenylpyridinium tetrafluoroborate initiating system activated by 660nm light emitting diodes is reported. The work demonstrates multiple uses of redlight initiated polymerisation in the preparation of monolithic stationary phases within polyimide and polyimide coated channels and the modification of monolithic materials with molecules which absorb strongly in the UV region. This initiator complex was used to synthesise poly(butyl methacrylateco- ethylene dimethacrylate) and poly(methyl methacrylate-co-ethylene dimethacrylate) monolithic stationary phases in polyimide coated fused silica capillaries of varying internal diameters, as well as within polyimide micro-fluidic chips.

Návaznosti

ED0001/01/01, projekt VaV

Název: CETOCOEN

GP203/09/P445, projekt VaV

Název: Luminiscenční a elektrochemická studie látek v ledu

Investor: Grantová agentura ČR, Luminiscenční a elektrochemická studie látek v ledu

MSM0021622413, záměr

Název: Proteiny v metabolismu a při interakci organismů s prostředím

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Proteiny v metabolismu a při interakci organismů s prostředím

MUNI/A/0980/2009, interní kód MU

Název: Molekulární a supramolekulární stavební bloky pro nanostrukturované materiály (Akronym: MOSTNAMAT)

Investor: Masarykova univerzita, Molekulární a supramolekulární stavební bloky pro nanostrukturované materiály, DO R. 2020_Kategorie A - Specifický výzkum - Studentské výzkumné projekty

Citovat

WALSH, Zarah, Paul A. LEVKIN, Silvija ABELE, Silvia SCARMAGNANI, Dominik HEGER, Petr KLÁN, Dermot DIAMOND, Brett PAULL, Frantisek SVEC a Miroslav MACKA. Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes. Journal of Chromatography A. Amsterdam: Elsevier, 2011, roč. 1218, č. 20, s. 2954–2962. ISSN 0021-9673. Dostupné z: https://dx.doi.org/10.1016/j.chroma.2011.03.021.

@article{935970,
   author = {Walsh, Zarah and Levkin, Paul A. and Abele, Silvija and Scarmagnani, Silvia and Heger, Dominik and Klán, Petr and Diamond, Dermot and Paull, Brett and Svec, Frantisek and Macka, Miroslav},
   article_location = {Amsterdam},
   article_number = {20},
   doi = {http://dx.doi.org/10.1016/j.chroma.2011.03.021},
   keywords = {Monolith Photo-initiated polymerisation Visible light Red LED Polyimide Micro-fluidic chips Grafting},
   language = {eng},
   issn = {0021-9673},
   journal = {Journal of Chromatography A},
   title = {Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes},
   volume = {1218},
   year = {2011}
}

TY  - JOUR
ID  - 935970
AU  - Walsh, Zarah - Levkin, Paul A. - Abele, Silvija - Scarmagnani, Silvia - Heger, Dominik - Klán, Petr - Diamond, Dermot - Paull, Brett - Svec, Frantisek - Macka, Miroslav
PY  - 2011
TI  - Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes
JF  - Journal of Chromatography A
VL  - 1218
IS  - 20
SP  - 2954–2962
EP  - 2954–2962
PB  - Elsevier
SN  - 00219673
KW  - Monolith Photo-initiated polymerisation Visible light Red LED Polyimide Micro-fluidic chips Grafting
N2  - An investigation into the preparation of monolithic separation media utilising a cyanine dye sensitiser/triphenylbutylborate/N-methoxy-4-phenylpyridinium tetrafluoroborate initiating system activated by 660nm light emitting diodes is reported. The work demonstrates multiple uses of redlight initiated polymerisation in the preparation of monolithic stationary phases within polyimide and polyimide coated channels and the modification of monolithic materials with molecules which absorb strongly in the UV region. This initiator complex was used to synthesise poly(butyl methacrylateco- ethylene dimethacrylate) and poly(methyl methacrylate-co-ethylene dimethacrylate) monolithic stationary phases in polyimide coated fused silica capillaries of varying internal diameters, as well as within polyimide micro-fluidic chips.
ER  -

WALSH, Zarah, Paul A. LEVKIN, Silvija ABELE, Silvia SCARMAGNANI, Dominik HEGER, Petr KLÁN, Dermot DIAMOND, Brett PAULL, Frantisek SVEC a Miroslav MACKA. Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes. \textit{Journal of Chromatography A}. Amsterdam: Elsevier, 2011, roč.~1218, č.~20, s.~2954–2962. ISSN~0021-9673. Dostupné z: https://dx.doi.org/10.1016/j.chroma.2011.03.021.

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