| SPÍCHAL, Zdeněk, Blanka VRBKOVÁ, Zdeněk MORAVEC, Jiří PINKAS and Marek NEČAS. Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands. Polyhedron. Velká Británie: Elsevier Science Ltd., 2011, vol. 30, No 9, p. 1620-1627. ISSN 0277-5387. |
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@article{936594,
author = {Spíchal, Zdeněk and Vrbková, Blanka and Moravec, Zdeněk and Pinkas, Jiří and Nečas, Marek},
article_location = {Velká Británie},
article_number = {9},
keywords = {Diphosphine dioxide;Lanthanides;Coordination polymers;Chelates;X-ray crystallography},
language = {eng},
issn = {0277-5387},
journal = {Polyhedron},
title = {Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands},
url = {http://dx.doi.org/10.1016/j.poly.2011.03.027},
volume = {30},
year = {2011}
}
TY - JOUR
ID - 936594
AU - Spíchal, Zdeněk - Vrbková, Blanka - Moravec, Zdeněk - Pinkas, Jiří - Nečas, Marek
PY - 2011
TI - Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands
JF - Polyhedron
VL - 30
IS - 9
SP - 1620-1627
EP - 1620-1627
PB - Elsevier Science Ltd.
SN - 02775387
KW - Diphosphine dioxide;Lanthanides;Coordination polymers;Chelates;X-ray crystallography
UR - http://dx.doi.org/10.1016/j.poly.2011.03.027
L2 - http://dx.doi.org/10.1016/j.poly.2011.03.027
N2 - Three large-bite diphosphine dioxide ligands were reacted with lanthanide salts to yield either molecular or polymeric complexes. The two flexible ligands gave bischelate complexes of general formulae [Ln(dppfO2)2Clx(NO3)2-x][FeCl4] and [Ln(dppdO2)2(NO3)2]NO3, where dppfO2 and dppdO2 are bis(diphenylphosphoryl) ferrocene and bis(diphenylphosphoryl)diphenyl ether, respectively. Reactions of the rigid bis(diphenylphosphoryl)benzene (dppbO2) with lanthanide salts yielded linear coordination polymers of a 1:1.5 metal-to-ligand stoichiometry. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, mass spectrometry, and TG/DSC techniques.
ER -
SPÍCHAL, Zdeněk, Blanka VRBKOVÁ, Zdeněk MORAVEC, Jiří PINKAS and Marek NEČAS. Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands. \textit{Polyhedron}. Velká Británie: Elsevier Science Ltd., 2011, vol.~30, No~9, p.~1620-1627. ISSN~0277-5387.
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