Detailed Information on Publication Record
2011
1,6-Dibenzylglycoluril for synthesis of deprotected glycoluril dimer
ŠTANCL, Marek, Muhammad Shamsul Azim KHAN and Vladimír ŠINDELÁŘBasic information
Original name
1,6-Dibenzylglycoluril for synthesis of deprotected glycoluril dimer
Authors
ŠTANCL, Marek (203 Czech Republic, belonging to the institution), Muhammad Shamsul Azim KHAN (50 Bangladesh, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution)
Edition
Tetrahedron, Oxford, England, Pergamon - Elsevier Science, 2011, 0040-4020
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10401 Organic chemistry
Country of publisher
United Kingdom of Great Britain and Northern Ireland
Confidentiality degree
není předmětem státního či obchodního tajemství
References:
Impact factor
Impact factor: 3.025
RIV identification code
RIV/00216224:14310/11:00050112
Organization unit
Faculty of Science
UT WoS
000296546700013
Keywords in English
glycolurils; deprotection; alkylation
Změněno: 20/4/2012 11:21, Ing. Andrea Mikešková
Abstract
V originále
1,6-Dibenzylglycoluril is not accessible via classical condensation reaction between substituted urea and glyoxal. In this paper 1,6-dibenzylglycoluril was successfully prepared by alkylation of 1,6-diacetylglycoluril with benzylbromide for the first time. 1,6-Dibenzylglycoluril reacted with formaldehyde to give tetrabenzylglycoluril dimer. Deprotection of this dimer and the previously reported o-xylyleneglycoluril dimer was achieved by dissolving metal reduction, whereas propyleneglycoluril dimer was deprotected by action of potassium persulfate.
Links
| ED0001/01/01, research and development project |
| ||
| GAP207/10/0695, research and development project |
| ||
| MUNI/A/0980/2009, interní kód MU |
|