Ferroceneboronic Acid for the Electrochemical Probing of
Interactions Involving Sugars

J 2011

Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars

LACINA, Karel a Petr SKLÁDAL

Základní údaje

Originální název

Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars

Název česky

Ferrocenboritá kyselina pro elektrochemické studium interakcí sacharidů

Autoři

LACINA, Karel (203 Česká republika, domácí) a Petr SKLÁDAL (203 Česká republika, garant, domácí)

Vydání

Electrochimica Acta, Amsterdam, Elsevier Science, 2011, 0013-4686

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10600 1.6 Biological sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 3.832

Kód RIV

RIV/00216224:14310/11:00054608

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.electacta.2011.09.019

UT WoS

000297399100077

Klíčová slova česky

voltametrie; boronátový komplex; amperometrie

Klíčová slova anglicky

voltammetry; boronate complex; amperometry

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 28. 12. 2011 20:50, prof. RNDr. Petr Skládal, CSc.

Anotace

ORIG CZ

V originále

Ferroceneboronic acid (FcBA) was used as a redox-active probe suitable for monitoring of diol-boronate interactions. Voltammetric and amperometric measurements allowed to detect FcBA forms - free and bound in the boronate complex. In this way, the complexation interaction was studied for a set of saccharide molecules as model diols and the corresponding affinity equilibrium constants were determined. A shift of the peak potential on voltammograms accompanying formation of the boronate complex with FcBA was proposed as a probe for electrochemical characterization of surface-confined diol-containing structures. The model experiments were carried out using sorbitol- and 1,6-hexandiol-modified polyepichlorhydrin conjugates deposited on the electrodes; the former compound was able to form the boronate complex while no change of the peak potential for the latter conjugate was observed. This approach seems promising for artificial bioelectronic affinity receptors and technology of reagentless biosensors where the binding interaction directly stimulates a measurable electrochemical event.

Česky

Kyselina ferrocenboritá sloužila k elektrochemickému studiu interakcí sacharidů (glukosa) a jiných polyolů (sorbitol) na základě tvorby boronátových komplexů s diolovým uskupením.

Návaznosti

LC06030, projekt VaV

Název: Biomolekulární centrum

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Biomolekulární centrum

Citovat

LACINA, Karel a Petr SKLÁDAL. Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars. Electrochimica Acta. Amsterdam: Elsevier Science, 2011, roč. 56, č. 27, s. 10246-10252. ISSN 0013-4686. Dostupné z: https://dx.doi.org/10.1016/j.electacta.2011.09.019.

@article{964157,
   author = {Lacina, Karel and Skládal, Petr},
   article_location = {Amsterdam},
   article_number = {27},
   doi = {http://dx.doi.org/10.1016/j.electacta.2011.09.019},
   keywords = {voltammetry; boronate complex; amperometry},
   language = {eng},
   issn = {0013-4686},
   journal = {Electrochimica Acta},
   title = {Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars},
   volume = {56},
   year = {2011}
}

TY  - JOUR
ID  - 964157
AU  - Lacina, Karel - Skládal, Petr
PY  - 2011
TI  - Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars
JF  - Electrochimica Acta
VL  - 56
IS  - 27
SP  - 10246-10252
EP  - 10246-10252
PB  - Elsevier Science
SN  - 00134686
KW  - voltammetry
KW  - boronate complex
KW  - amperometry
N2  - Ferroceneboronic acid (FcBA) was used as a redox-active probe suitable for monitoring of diol-boronate interactions. Voltammetric and amperometric measurements allowed to detect FcBA forms - free and bound in the boronate complex. In this way, the complexation interaction was studied for a set of saccharide molecules as model diols and the corresponding affinity equilibrium constants were determined. A shift of the peak potential on voltammograms accompanying formation of the boronate complex with FcBA was proposed as a probe for electrochemical characterization of surface-confined diol-containing structures. The model experiments were carried out using sorbitol- and 1,6-hexandiol-modified polyepichlorhydrin conjugates deposited on the electrodes; the former compound was able to form the boronate complex while no change of the peak potential for the latter conjugate was observed. This approach seems promising for artificial bioelectronic affinity receptors and technology of reagentless biosensors where the binding interaction directly stimulates a measurable electrochemical event.
ER  -

LACINA, Karel a Petr SKLÁDAL. Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars. \textit{Electrochimica Acta}. Amsterdam: Elsevier Science, 2011, roč.~56, č.~27, s.~10246-10252. ISSN~0013-4686. Dostupné z: https://dx.doi.org/10.1016/j.electacta.2011.09.019.

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