C6740 Electrical Properties of Dielectrics

Faculty of Science
Spring 2024
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Taught in person.
Teacher(s)
prof. RNDr. Libuše Trnková, CSc. (lecturer)
Guaranteed by
prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Mon 19. 2. to Sun 26. 5. Thu 16:00–17:50 C12/311
Prerequisites
knowledge of general and physical chemistry
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The aim of the course is: understanding the molecule as an electrical charge system; the behavior of dielectrics in the electric field; how the dipole moment is calculated and evaluated and how it relates to the structure of the molecule; what are the possibilities for measuring and computing dipole moments. The course the topics: (a)dielectric properties of liquids, crystals and colloidal systems; (b) intermolecular interactions; (c) dielectric loss, relaxation time together with the kinetic theory of dielectric relaxation and viscosity. The course takes into account the adsorption of molecules on the phase interface, the proton or ion transfer complexes and the charge transfer complexes.
Learning outcomes
After graduation of this course the student will be able: - to characterize and evaluate intermolecular interactions of different types (non-covalent interactions); - describe the behavior of dielectrics in the electric field; - determine dipole moments; - evaluate charge transfer processes.
Syllabus
  • 1. Molecule as a system of electric charges. Properties of molecules conditioned by permanent and changing electron density.

    2. Dielectrics in an electric field.

    3. Dipole moments (DM) and structure of molecules, measurements and calculations of DM.

    4. Dielectric properties of liquids, crystals and colloid systems.

    5. Intermolecular interactions.

    6. Dielectric loss, time relaxation, kinetic theory of dielectric relaxation.

    7. Optical effects due to interaction of molecules with electromagnetic radiation.

    8. Adsorption of molecules at interface, influence of electric field.

    9. Complexes with proton or ion transfer.

    10. Charge transfer complexes.
Literature
  • ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
  • ATKINS, Peter William. The elements of physical chemistry [Atkins, 1992]. Oxford: Oxford University Press, 1992, 11, 496 s. ISBN 0-19-855723-X. info
  • EXNER, Otto. Struktura a fyzikální vlastnosti organických sloučenin. 1. vyd. Praha: Státní nakladatelství technické literatury, 1985, 275 s. info
  • HOLBA, Vladislav. Fyzikálno-chemické vlastnosti atómov a molekúl. 1. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1980, 282 s. info
  • VOL'KENŠTEJN, Michail Vladimirovič. Struktura a fysikální vlastnosti molekul. Translated by Jiří Dvořák. 1. vyd. Praha: Nakladatelství České akademie věd, 1962, 721 s. info
Teaching methods
Lecture with exercises.
Assessment methods
written test, oral examination
Language of instruction
Czech
Follow-Up Courses
Further Comments
Study Materials
The course is taught annually.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2011 - only for the accreditation, Spring 2000, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Spring 2008, Spring 2009, Spring 2010, Spring 2011, Spring 2012, spring 2012 - acreditation, Spring 2014, Spring 2015, Spring 2016, Spring 2017, spring 2018, Spring 2019, Spring 2020, Spring 2021, Spring 2022, Spring 2023, Spring 2025.
  • Enrolment Statistics (recent)
  • Permalink: https://is.muni.cz/course/sci/spring2024/C6740