Crystal structure of pseudojohannite, with a revised formula
Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12

J 2012

Crystal structure of pseudojohannite, with a revised formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12

PLÁŠIL, Jakub; Karla FEJFAROVÁ; Kia Sheree WALLWORK; Michal DUŠEK; Radek ŠKODA et al.

Základní údaje

Originální název

Crystal structure of pseudojohannite, with a revised formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12

Autoři

PLÁŠIL, Jakub; Karla FEJFAROVÁ; Kia Sheree WALLWORK; Michal DUŠEK; Radek ŠKODA; Jiří SEJKORA; Jiří ČEJKA; František VESELOVSKÝ; Jan HLOUŠEK; Nicolas MEISSER a Joel BRUGGER

Vydání

American Mineralogist, CHANTILLY, Mineralogical Society of America, 2012, 0003-004X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10302 Condensed matter physics

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.204

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/12:00064318

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.2138/am.2012.4127

UT WoS

000309645500027

Klíčová slova anglicky

Pseudojohannite; zippeite group; uranyl sulfate; X ray diffraction; crystal structure; chemical composition

Štítky

AKR, rivok

Změněno: 9. 4. 2013 16:08, Ing. Andrea Mikešková

Anotace

V originále

The crystal structure of pseudojohannite from White Canyon, Utah, was solved by charge-flipping from single-crystal X-ray diffraction data and refined to an Robs = 0.0347, based on 2664 observed reflections. Pseudojohannite from White Canyon is triclinic, P-1, with a = 8.6744(4), b = 8.8692(4), c = 10.0090(5) A, alpha = 72.105(4)degrees, beta = 70.544(4)degrees, gamma = 76.035(4)degrees, and V = 682.61(5) A^3, with Z = 1 and chemical formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12. The crystal structure of pseudojohannite is built up from sheets of zippeite topology that do not contain any OH groups; these sheets are identical to those found in zippeites containing Mg2+, Co2+, and Zn2+. The two Cu2+ sites in pseudojohannite are [5]- and [6]-coordinated by H2O molecules and OH groups. The crystal structure of the pseudojohannite holotype specimen from Jáchymov was refined using Rietveld refinement of high-resolution powder diffraction data. Results indicate that the crystal structures of pseudojohannite from White Canyon and Jáchymov are identical.

Návaznosti

EE2.3.20.0052, projekt VaV

Název: Výzkumný tým pro ukládání radioaktivních odpadů a jadernou bezpečnost

Citovat

PLÁŠIL, Jakub; Karla FEJFAROVÁ; Kia Sheree WALLWORK; Michal DUŠEK; Radek ŠKODA; Jiří SEJKORA; Jiří ČEJKA; František VESELOVSKÝ; Jan HLOUŠEK; Nicolas MEISSER a Joel BRUGGER. Crystal structure of pseudojohannite, with a revised formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12. American Mineralogist. CHANTILLY: Mineralogical Society of America, 2012, roč. 97, č. 10, s. 1796-1803. ISSN 0003-004X. Dostupné z: https://doi.org/10.2138/am.2012.4127.

@article{1090707,
   author = {Plášil, Jakub and Fejfarová, Karla and Wallwork, Kia Sheree and Dušek, Michal and Škoda, Radek and Sejkora, Jiří and Čejka, Jiří and Veselovský, František and Hloušek, Jan and Meisser, Nicolas and Brugger, Joel},
   article_location = {CHANTILLY},
   article_number = {10},
   doi = {https://doi.org/10.2138/am.2012.4127},
   keywords = {Pseudojohannite; zippeite group; uranyl sulfate; X ray diffraction; crystal structure; chemical composition},
   language = {eng},
   issn = {0003-004X},
   journal = {American Mineralogist},
   title = {Crystal structure of pseudojohannite, with a revised formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12},
   volume = {97},
   year = {2012}
}

TY  - JOUR
ID  - 1090707
AU  - Plášil, Jakub - Fejfarová, Karla - Wallwork, Kia Sheree - Dušek, Michal - Škoda, Radek - Sejkora, Jiří - Čejka, Jiří - Veselovský, František - Hloušek, Jan - Meisser, Nicolas - Brugger, Joel
PY  - 2012
TI  - Crystal structure of pseudojohannite, with a revised formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12
JF  - American Mineralogist
VL  - 97
IS  - 10
SP  - 1796-1803
EP  - 1796-1803
PB  - Mineralogical Society of America
SN  - 0003004X
KW  - Pseudojohannite
KW  - zippeite group
KW  - uranyl sulfate
KW  - X ray diffraction
KW  - crystal structure
KW  - chemical composition
N2  - The crystal structure of pseudojohannite from White Canyon, Utah, was solved by charge-flipping from single-crystal X-ray diffraction data and refined to an Robs = 0.0347, based on 2664 observed reflections. Pseudojohannite from White Canyon is triclinic, P-1, with a = 8.6744(4), b = 8.8692(4), c = 10.0090(5) A, alpha = 72.105(4)degrees, beta = 70.544(4)degrees, gamma = 76.035(4)degrees, and V = 682.61(5) A^3, with Z = 1 and chemical formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12. The crystal structure of pseudojohannite is built up from sheets of zippeite topology that do not contain any OH groups; these sheets are identical to those found in zippeites containing Mg2+, Co2+, and Zn2+. The two Cu2+ sites in pseudojohannite are [5]- and [6]-coordinated by H2O molecules and OH groups. The crystal structure of the pseudojohannite holotype specimen from Jáchymov was refined using Rietveld refinement of high-resolution powder diffraction data. Results indicate that the crystal structures of pseudojohannite from White Canyon and Jáchymov are identical.
ER  -

PLÁŠIL, Jakub; Karla FEJFAROVÁ; Kia Sheree WALLWORK; Michal DUŠEK; Radek ŠKODA; Jiří SEJKORA; Jiří ČEJKA; František VESELOVSKÝ; Jan HLOUŠEK; Nicolas MEISSER a Joel BRUGGER. Crystal structure of pseudojohannite, with a revised formula Cu3(OH)2[(UO2)4O4(SO4)2](H2O)12. \textit{American Mineralogist}. CHANTILLY: Mineralogical Society of America, 2012, roč.~97, č.~10, s.~1796-1803. ISSN~0003-004X. Dostupné z: https://doi.org/10.2138/am.2012.4127.

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