Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate
mineral from Jáchymov, Czech Republic.

J 2012

Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jáchymov, Czech Republic.

PLÁŠIL, Jakub; Jan HLOUŠEK; František VESELOVSKÝ; Karla FEJFAROVÁ; Michal DUŠEK et al.

Základní údaje

Originální název

Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jáchymov, Czech Republic.

Autoři

PLÁŠIL, Jakub; Jan HLOUŠEK; František VESELOVSKÝ; Karla FEJFAROVÁ; Michal DUŠEK; Radek ŠKODA; Milan NOVÁK; Jiří ČEJKA; Jiří SEJKORA a Petr ONDRUŠ

Vydání

American Mineralogist, 2012, 0003-004X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10302 Condensed matter physics

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.204

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/12:00064364

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.2138/am.2012.3976

UT WoS

000300209500022

Klíčová slova anglicky

Adolfpateraite uranyl sulfate crystal structure chemical composition Jáchymov

Štítky

AKR, rivok

Změněno: 16. 7. 2013 09:37, Ing. Andrea Mikešková

Anotace

V originále

Adolfpateraite, monoclinic K(UO2)(SO4)(OH)(H2O), is a new supergene mineral from the Svornost mine, Jáchymov ore district, Czech Republic. It forms sulfur yellow to greenish yellow crystalline aggregates, up to 2 mm in diameter. Crystals are transparent to translucent with a vitreous luster, without observable cleavage. The streak is pale yellow. The Mohs hardness is ~2. The mineral shows a green fluorescence in long-wave ultraviolet radiation. Adolfpateraite is pleochroic, with alpha = colorless and gamma = yellow (beta could not been examined). It is biaxial, with alfa = 1.597(2), gama = 1.659(2) (beta could not been measured), birefringence 0.062. The empirical chemical formula (mean of 4 electron microprobe point analyses) was calculated based on 8 O apfu and is K0.94(UO2)1.00(SO4)1.02(OH)0.90(H2O)1.00 (water content calculated). The simplified formula is K(UO2)(SO4)(OH)(H2O), requiring K2O 10.70, UO3 64.97, SO3 18.19, H2O 6.14, total 100.00 wt%. Adolfpateraite is monoclinic, space group P21/c, a = 8.0462(1), b = 7.9256(1), c = 11.3206(2) A, beta = 107.726(2), V = 687.65(2) A^3, Z = 4, and Dcalc = 4.24 g/cm3. The five strongest reflections in the X-ray powder diffraction pattern are [dobs in Angstroms (I) (hkl)]: 7.658 (76) (100), 5.386 (100) (002), 5.218 (85) (102), 3.718 (46) (021), 3.700 (37) (202). The crystal structure has been refined from single-crystal X-ray diffraction data to R1 = 0.0166 with GOF = 1.30, based on 1915 observed reflections [Iobs > 3sigma(I)]. The crystal structure consists of chains of uranyl polyhedra extended along [010], with OH located on the shared vertex between the bipyramids. The sulfate tetrahedra decorate the outer side of the chain with bridging bidentate linkages between the uranyl pentagonal bipyramids.

Návaznosti

MSM0021622412, záměr

Název: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Akronym: INCHEMBIOL)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální , regionální a lokální úrovni

Citovat

PLÁŠIL, Jakub; Jan HLOUŠEK; František VESELOVSKÝ; Karla FEJFAROVÁ; Michal DUŠEK; Radek ŠKODA; Milan NOVÁK; Jiří ČEJKA; Jiří SEJKORA a Petr ONDRUŠ. Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jáchymov, Czech Republic. American Mineralogist. 2012, roč. 97, 2-3, s. 447-454. ISSN 0003-004X. Dostupné z: https://doi.org/10.2138/am.2012.3976.

@article{1091371,
   author = {Plášil, Jakub and Hloušek, Jan and Veselovský, František and Fejfarová, Karla and Dušek, Michal and Škoda, Radek and Novák, Milan and Čejka, Jiří and Sejkora, Jiří and Ondruš, Petr},
   article_number = {2-3},
   doi = {https://doi.org/10.2138/am.2012.3976},
   keywords = {Adolfpateraite uranyl sulfate crystal structure chemical composition Jáchymov},
   language = {eng},
   issn = {0003-004X},
   journal = {American Mineralogist},
   title = {Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jáchymov, Czech Republic.},
   volume = {97},
   year = {2012}
}

TY  - JOUR
ID  - 1091371
AU  - Plášil, Jakub - Hloušek, Jan - Veselovský, František - Fejfarová, Karla - Dušek, Michal - Škoda, Radek - Novák, Milan - Čejka, Jiří - Sejkora, Jiří - Ondruš, Petr
PY  - 2012
TI  - Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jáchymov, Czech Republic.
JF  - American Mineralogist
VL  - 97
IS  - 2-3
SP  - 447-454
EP  - 447-454
SN  - 0003004X
KW  - Adolfpateraite uranyl sulfate crystal structure chemical composition Jáchymov
N2  - Adolfpateraite, monoclinic K(UO2)(SO4)(OH)(H2O), is a new supergene mineral from the Svornost mine, Jáchymov ore district, Czech Republic. It forms sulfur yellow to greenish yellow crystalline aggregates, up to 2 mm in diameter. Crystals are transparent to translucent with a vitreous luster, without observable cleavage. The streak is pale yellow. The Mohs hardness is ~2. The mineral shows a green fluorescence in long-wave ultraviolet radiation. Adolfpateraite is pleochroic, with alpha = colorless and gamma = yellow (beta could not been examined). It is biaxial, with alfa = 1.597(2), gama = 1.659(2) (beta could not been measured), birefringence 0.062. The empirical chemical formula (mean of 4 electron microprobe point analyses) was calculated based on 8 O apfu and is K0.94(UO2)1.00(SO4)1.02(OH)0.90(H2O)1.00 (water content calculated). The simplified formula is K(UO2)(SO4)(OH)(H2O), requiring K2O 10.70, UO3 64.97, SO3 18.19, H2O 6.14, total 100.00 wt%. Adolfpateraite is monoclinic, space group P21/c, a = 8.0462(1), b = 7.9256(1), c = 11.3206(2) A, beta = 107.726(2), V = 687.65(2) A^3, Z = 4, and Dcalc = 4.24 g/cm3. The five strongest reflections in the X-ray powder diffraction pattern are [dobs in Angstroms (I) (hkl)]: 7.658 (76) (100), 5.386 (100) (002), 5.218 (85) (102), 3.718 (46) (021), 3.700 (37) (202). The crystal structure has been refined from single-crystal X-ray diffraction data to R1 = 0.0166 with GOF = 1.30, based on 1915 observed reflections [Iobs > 3sigma(I)]. The crystal structure consists of chains of uranyl polyhedra extended along [010], with OH located on the shared vertex between the bipyramids. The sulfate tetrahedra decorate the outer side of the chain with bridging bidentate linkages between the uranyl pentagonal bipyramids.
ER  -

PLÁŠIL, Jakub; Jan HLOUŠEK; František VESELOVSKÝ; Karla FEJFAROVÁ; Michal DUŠEK; Radek ŠKODA; Milan NOVÁK; Jiří ČEJKA; Jiří SEJKORA a Petr ONDRUŠ. Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jáchymov, Czech Republic. \textit{American Mineralogist}. 2012, roč.~97, 2-3, s.~447-454. ISSN~0003-004X. Dostupné z: https://doi.org/10.2138/am.2012.3976.

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