a 2012

PROVENANCE STUDY OF ARCHAEOLOGICAL RAW MATERIAL USING LA-ICP-MS

HUŠKOVÁ, Simona; Tomáš VACULOVIČ; Lubomír PROKEŠ; Antonín PŘICHYSTAL; Viktor KANICKÝ et al.

Základní údaje

Originální název

PROVENANCE STUDY OF ARCHAEOLOGICAL RAW MATERIAL USING LA-ICP-MS

Název anglicky

PROVENANCE STUDY OF ARCHAEOLOGICAL RAW MATERIAL USING LA-ICP-MS

Vydání

European Symposium on Atomic Spectrometry ESAS 2012, XXth Slovak - Czech Spectroscopic Conference, 2012

Další údaje

Jazyk

čeština

Typ výsledku

Konferenční abstrakt

Obor

10406 Analytical chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/12:00064397

Organizační jednotka

Přírodovědecká fakulta

ISBN

978-80-223-3292-7

Klíčová slova česky

laserová ablace; LA-ICP-MS; provenience; porcelanity; štípaná kamenná industrie

Klíčová slova anglicky

laser ablation; LA-ICP-MS; provenance; porcellanite; stone industry

Příznaky

Mezinárodní význam
Změněno: 19. 3. 2013 11:41, Bc. Mgr. Simona Turková

Anotace

V originále

With the increasing interest of archaeologists and geologists in ancient raw materials and their provenance there was a need to develop nondestructive analytical methods with low limits of detection. Such a method with a low level of destructivity can be LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry). One of the major benefits of LA-ICP-MS method is a relatively simple sample preparation or even no preparation of the analyzed sample. On the other hand simple sample preparation is disadvantaged by relatively difficult process of optimization of the measuring parameters such as pulse frequency, diameter of a laser beam and its energy. Also the process of data calibration and quantification is quite complicated and requires the use of standard reference material. This work presents preliminary results of LA-ICP-MS analysis of samples made from porcellanite, which was commonly used as a raw material for manufacturing stone tools in the past. Set of analyzed samples included both source material and artifacts mainly from Czech Republic. One sample came also from Poland. NIST SRM 610 was used as a calibration material for quantification purposes. The resulting data were than subjected to multivariate statistics including Principal component analysis (PCA), which represents an essential part of multivariate data analysis. Our results indicate that LA-ICP-MS is a suitable method for provenance determination of the porcellanite material.

Anglicky

With the increasing interest of archaeologists and geologists in ancient raw materials and their provenance there was a need to develop nondestructive analytical methods with low limits of detection. Such a method with a low level of destructivity can be LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry). One of the major benefits of LA-ICP-MS method is a relatively simple sample preparation or even no preparation of the analyzed sample. On the other hand simple sample preparation is disadvantaged by relatively difficult process of optimization of the measuring parameters such as pulse frequency, diameter of a laser beam and its energy. Also the process of data calibration and quantification is quite complicated and requires the use of standard reference material. This work presents preliminary results of LA-ICP-MS analysis of samples made from porcellanite, which was commonly used as a raw material for manufacturing stone tools in the past. Set of analyzed samples included both source material and artifacts mainly from Czech Republic. One sample came also from Poland. NIST SRM 610 was used as a calibration material for quantification purposes. The resulting data were than subjected to multivariate statistics including Principal component analysis (PCA), which represents an essential part of multivariate data analysis. Our results indicate that LA-ICP-MS is a suitable method for provenance determination of the porcellanite material.

Návaznosti

ME10012, projekt VaV
Název: Laserová ablace se spektrometrií v indukčně vázaném plazmatu a spektroskopie laserem buzeného mikroplazmatu v archeologii a antropologii (Akronym: LAICPMSOES a LIBS v arch. a antrop.)
Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Laserová ablace se spektrometrií v indukčně vázaném plazmatu a spektroskopie laserem buzeného mikroplazmatu v archeologii a antropologii, Program výzkumu a vývoje KONTAKT (ME)