Provenance study of volcanic glass using 266-1064 nm orthogonal
double pulse laser induced breakdown spectroscopy

J 2013

Provenance study of volcanic glass using 266-1064 nm orthogonal double pulse laser induced breakdown spectroscopy

HRDLIČKA, Aleš; Lubomír PROKEŠ; Michaela VAŠINOVÁ GALIOVÁ; Karel NOVOTNÝ; Anna VITEŠNÍKOVÁ et al.

Základní údaje

Originální název

Provenance study of volcanic glass using 266-1064 nm orthogonal double pulse laser induced breakdown spectroscopy

Název česky

Provenienční studie vulkanického skla pomocí 266-1064 nm ortogonální dvoupulzní spektrometrie laseem buzeného mikroplazmatu

Autoři

HRDLIČKA, Aleš; Lubomír PROKEŠ; Michaela VAŠINOVÁ GALIOVÁ; Karel NOVOTNÝ; Anna VITEŠNÍKOVÁ; Tereza HELEŠICOVÁ a Viktor KANICKÝ

Vydání

Chemical Papers, Warsaw, Versita, 2013, 0366-6352

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Polsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 1.193

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14740/13:00067988

Organizační jednotka

Středoevropský technologický institut

DOI

https://doi.org/10.2478/s11696-013-0332-x

UT WoS

000314882900010

Klíčová slova česky

dvoupulzní; spektroskopie laserem buzeného mikroplazmatu; sopečné sklo; obsidián; provenienční studie multidimenzionální statistika;

Klíčová slova anglicky

double pulse; laser induced breakdown spectroscopy; volcanic glass; obsidian; multidimensional statistics; provenance study

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 6. 4. 2014 14:02, Olga Křížová

Anotace

ORIG CZ

V originále

Double pulse laser induced breakdown spectroscopy in orthogonal configuration was used for the analysis of twelve samples of volcanic glass. Raw material and artifact samples originated from Czech, Slovak, German, Hungarian, Greek, Turkish, and Ukrainian sites. The primary 266 nm laser beam was focused onto a sample area of about 0.1 mm in diameter at the optimised energy of 10 mJ resulting in only very slight sample damage, almost unrecognizable even by a microscope. The secondary 1064 nm laser beam, positioned parallel to the sample surface and focused onto the intersection with the primary beam, induced a spark with enhanced radiation at the optimised energy of 100 mJ. Measurement of emission lines selected on basis of chemical composition, signal intensity, signal-to-background ratio, and minimum interference from the surrounding spectra: Si(I) 288.16 nm, Mg(II) 279.55 nm, 280.27 nm, Mg(I) 285.21 nm, Ca(II) 317.93 nm, Na(I) 589.59 nm, Al(I) 308.22 nm, Fe(II) 259.94 nm, Ti(II) 334.94 nm, Sr(II) 407.77 nm, Ba(II) 455.40 nm, K(I) 769.90 nm, provided experimental data sufficiently sensitive to differentiate the properties of the studied samples. Rare earth elements were not detected even though the double pulse technique is more sensitive than the single pulse variant. Visualisation methods of multidimensional statistical analyses such as radar chart, Chernoff faces, scatterplots, and the Spearman correlation matrix provided successful differentiation of the sample groups and/or particular samples by their origin.

Česky

Dvoupulzní spektroskopie laserem buzeného mikroplazmatu v ortogonálním uspořádání byla použita při provedení provenienční studie sopečného skla.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

ME10012, projekt VaV

Název: Laserová ablace se spektrometrií v indukčně vázaném plazmatu a spektroskopie laserem buzeného mikroplazmatu v archeologii a antropologii (Akronym: LAICPMSOES a LIBS v arch. a antrop.)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Laserová ablace se spektrometrií v indukčně vázaném plazmatu a spektroskopie laserem buzeného mikroplazmatu v archeologii a antropologii, Program výzkumu a vývoje KONTAKT (ME)

Citovat

HRDLIČKA, Aleš; Lubomír PROKEŠ; Michaela VAŠINOVÁ GALIOVÁ; Karel NOVOTNÝ; Anna VITEŠNÍKOVÁ; Tereza HELEŠICOVÁ a Viktor KANICKÝ. Provenance study of volcanic glass using 266-1064 nm orthogonal double pulse laser induced breakdown spectroscopy. Chemical Papers. Warsaw: Versita, 2013, roč. 67, č. 5, s. 546-555. ISSN 0366-6352. Dostupné z: https://doi.org/10.2478/s11696-013-0332-x.

@article{1093568,
   author = {Hrdlička, Aleš and Prokeš, Lubomír and Vašinová Galiová, Michaela and Novotný, Karel and Vitešníková, Anna and Helešicová, Tereza and Kanický, Viktor},
   article_location = {Warsaw},
   article_number = {5},
   doi = {https://doi.org/10.2478/s11696-013-0332-x},
   keywords = {double pulse; laser induced breakdown spectroscopy; volcanic glass; obsidian; multidimensional statistics; provenance study},
   language = {eng},
   issn = {0366-6352},
   journal = {Chemical Papers},
   title = {Provenance study of volcanic glass using 266-1064 nm orthogonal double pulse laser induced breakdown spectroscopy},
   url = {http://link.springer.com/article/10.2478%2Fs11696-013-0332-x},
   volume = {67},
   year = {2013}
}

TY  - JOUR
ID  - 1093568
AU  - Hrdlička, Aleš - Prokeš, Lubomír - Vašinová Galiová, Michaela - Novotný, Karel - Vitešníková, Anna - Helešicová, Tereza - Kanický, Viktor
PY  - 2013
TI  - Provenance study of volcanic glass using 266-1064 nm orthogonal double pulse laser induced breakdown spectroscopy
JF  - Chemical Papers
VL  - 67
IS  - 5
SP  - 546-555
EP  - 546-555
PB  - Versita
SN  - 03666352
KW  - double pulse
KW  - laser induced breakdown spectroscopy
KW  - volcanic glass
KW  - obsidian
KW  - multidimensional statistics
KW  - provenance study
UR  - http://link.springer.com/article/10.2478%2Fs11696-013-0332-x
L2  - http://link.springer.com/article/10.2478%2Fs11696-013-0332-x
N2  - Double pulse laser induced breakdown spectroscopy in orthogonal configuration was used for the analysis of twelve samples of volcanic glass. Raw material and artifact samples originated from Czech, Slovak, German, Hungarian, Greek, Turkish, and Ukrainian sites. The primary 266 nm laser beam was focused onto a sample area of about 0.1 mm in diameter at the optimised energy of 10 mJ resulting in only very slight sample damage, almost unrecognizable even by a microscope. The secondary 1064 nm laser beam, positioned parallel to the sample surface and focused onto the intersection with the primary beam, induced a spark with enhanced radiation at the optimised energy of 100 mJ. Measurement of emission lines selected on basis of chemical composition, signal intensity, signal-to-background ratio, and minimum interference from the surrounding spectra: Si(I) 288.16 nm, Mg(II) 279.55 nm, 280.27 nm, Mg(I) 285.21 nm, Ca(II) 317.93 nm, Na(I) 589.59 nm, Al(I) 308.22 nm, Fe(II) 259.94 nm, Ti(II) 334.94 nm, Sr(II) 407.77 nm, Ba(II) 455.40 nm, K(I) 769.90 nm, provided experimental data sufficiently sensitive to differentiate the properties of the studied samples. Rare earth elements were not detected even though the double pulse technique is more sensitive than the single pulse variant. Visualisation methods of multidimensional statistical analyses such as radar chart, Chernoff faces, scatterplots, and the Spearman correlation matrix provided successful differentiation of the sample groups and/or particular samples by their origin.
ER  -

HRDLIČKA, Aleš; Lubomír PROKEŠ; Michaela VAŠINOVÁ GALIOVÁ; Karel NOVOTNÝ; Anna VITEŠNÍKOVÁ; Tereza HELEŠICOVÁ a Viktor KANICKÝ. Provenance study of volcanic glass using 266-1064 nm orthogonal double pulse laser induced breakdown spectroscopy. \textit{Chemical Papers}. Warsaw: Versita, 2013, roč.~67, č.~5, s.~546-555. ISSN~0366-6352. Dostupné z: https://doi.org/10.2478/s11696-013-0332-x.

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