Metallosilicates prepared by non-hydrolytic condensation
reactions

a 2013

Metallosilicates prepared by non-hydrolytic condensation reactions

ŠKODA, David; Aleš STÝSKALÍK; Zdeněk MORAVEC; Jiří PINKAS; Craig BARNES et al.

Základní údaje

Originální název

Metallosilicates prepared by non-hydrolytic condensation reactions

Autoři

ŠKODA, David; Aleš STÝSKALÍK; Zdeněk MORAVEC; Jiří PINKAS a Craig BARNES

Vydání

The 246th ACS National Meeting, Indianapolis, Indiana, USA, 2013

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14740/13:00069406

Organizační jednotka

Středoevropský technologický institut

UT WoS

000329618404651

Klíčová slova anglicky

non-hydrolytic; inorganic-organic; metallosilicates

Změněno: 11. 10. 2013 16:53, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

Non-hydrolytic sol-gel reactions are efficient alternatives to classical aqueous techniques for synthesis of multimetallic oxides and inorganic-organic hybrid materials. We developed non-hydrolytic sol-gel routes to several groups of metallosilicate hybrid inorganic-organic materials based on polycondensation reactions. Titanosilicate xerogels were prepared by reactions between Ti(NEt2)4 or Ti(OR)4, R = OiPr, OtBu and Si(OAc)4. These non-hydrolytic polycondensation reactions led to the formation of Si-O-Ti bonds and to release of acetic acid ester and diethylacetamide as byproducts, respectively. Then the catalytic activity of xerogels in epoxidation of cyclohexene was studied. Alumosilicates were prepared by reactions between Al(NMe2)3 or Al(OiPr)3 and acetoxysilanes R4-nSi(OAc)n, n = 1-4 and R = Me, Ph, H, OtBu. In this case these non-hydrolytic condensation reactions proceeded with the formation of Si-O-Al networks and dimethylacetamide or acetic acid ester and as byproducts as well. As a further step, bridged bis(triacetoxysilyl)alkanes (AcO)3Si(CH2)xSi(OAc)3 , x = 1, 2, 3, 6 were used for the synthesis. Using alkylacetoxysilanes as silicon precursors we can modify some physico-chemical properties (hydrophobicity, porosity) of the resulting xerogels. We have examined also the surface modification of xerogels at the residual organic groups and established their acidic properties. The resulting xerogels and volatile byproducts were characterized by liquid and solid-state NMR, IR, GC-MS, surface area analysis, TGA, and XRD.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

LH11028, projekt VaV

Název: Nehydrolytické sol-gelové reakce pro přípravu křemičitanů a fosforečnanů s řízenou porozitou a funkčními skupinami na povrchu (Akronym: NHSGKNOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Nehydrolytické sol-gelové reakce pro přípravu křemičitanů a fosforečnanů s řízenou porozitou a funkčními skupinami na povrchu

Citovat

ŠKODA, David; Aleš STÝSKALÍK; Zdeněk MORAVEC; Jiří PINKAS a Craig BARNES. Metallosilicates prepared by non-hydrolytic condensation reactions. In The 246th ACS National Meeting, Indianapolis, Indiana, USA. 2013.

@proceedings{1122964,
   author = {Škoda, David and Stýskalík, Aleš and Moravec, Zdeněk and Pinkas, Jiří and Barnes, Craig},
   booktitle = {The 246th ACS National Meeting, Indianapolis, Indiana, USA},
   keywords = {non-hydrolytic; inorganic-organic; metallosilicates},
   language = {eng},
   title = {Metallosilicates prepared by non-hydrolytic condensation reactions},
   year = {2013}
}

TY  - CONF
ID  - 1122964
AU  - Škoda, David - Stýskalík, Aleš - Moravec, Zdeněk - Pinkas, Jiří - Barnes, Craig
PY  - 2013
TI  - Metallosilicates prepared by non-hydrolytic condensation reactions
KW  - non-hydrolytic
KW  - inorganic-organic
KW  - metallosilicates
N2  - Non-hydrolytic sol-gel reactions are efficient alternatives to classical aqueous techniques for synthesis of multimetallic oxides and inorganic-organic hybrid materials. We developed non-hydrolytic sol-gel routes to several groups of metallosilicate hybrid inorganic-organic materials based on polycondensation reactions. Titanosilicate xerogels were prepared by reactions between Ti(NEt2)4 or Ti(OR)4, R = OiPr, OtBu and Si(OAc)4. These non-hydrolytic polycondensation reactions led to the formation of Si-O-Ti bonds and to release of acetic acid ester and diethylacetamide as byproducts, respectively. Then the catalytic activity of xerogels in epoxidation of cyclohexene was studied. Alumosilicates were prepared by reactions between Al(NMe2)3 or Al(OiPr)3 and acetoxysilanes R4-nSi(OAc)n, n = 1-4 and R = Me, Ph, H, OtBu. In this case these non-hydrolytic condensation reactions proceeded with the formation of Si-O-Al networks and dimethylacetamide or acetic acid ester and as byproducts as well. As a further step, bridged bis(triacetoxysilyl)alkanes (AcO)3Si(CH2)xSi(OAc)3 , x = 1, 2, 3, 6 were used for the synthesis. Using alkylacetoxysilanes as silicon precursors we can modify some physico-chemical properties (hydrophobicity, porosity) of the resulting xerogels. We have examined also the surface modification of xerogels at the residual organic groups and established their acidic properties. The resulting xerogels and volatile byproducts were characterized by liquid and solid-state NMR, IR, GC-MS, surface area analysis, TGA, and XRD.
ER  -

ŠKODA, David; Aleš STÝSKALÍK; Zdeněk MORAVEC; Jiří PINKAS a Craig BARNES. Metallosilicates prepared by non-hydrolytic condensation reactions. In \textit{The 246th ACS National Meeting, Indianapolis, Indiana, USA}. 2013.

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