| KRAJCAROVÁ, Lucie, Karel NOVOTNÝ, Petr BABULA, Ivo PROVAZNÍK, Petra PROCHAZKOVÁ, Vojtěch ADAM, Madhavi Z. MARTIN, René KIZEK a Jozef KAISER. Copper Transport and Accumulation in Spruce Stems (Picea abies (L.) Karsten) Revealed by Laser-Induced Breakdown Spectroscopy. International Journal of Electrochemical Science. Belgrade: ESG, 2013, roč. 8, č. 4, s. 4485-4504. ISSN 1452-3981. |
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@article{1137242,
author = {Krajcarová, Lucie and Novotný, Karel and Babula, Petr and Provazník, Ivo and Prochazková, Petra and Adam, Vojtěch and Martin, Madhavi Z. and Kizek, René and Kaiser, Jozef},
article_location = {Belgrade},
article_number = {4},
keywords = {Electrochemical Detection; Double-pulse LIBS; Fluorescence Microscopy; Elemental Distribution; Mass Spectrometry},
language = {eng},
issn = {1452-3981},
journal = {International Journal of Electrochemical Science},
title = {Copper Transport and Accumulation in Spruce Stems (Picea abies (L.) Karsten) Revealed by Laser-Induced Breakdown Spectroscopy},
url = {http://www.electrochemsci.org/papers/vol8/80404485.pdf},
volume = {8},
year = {2013}
}
TY - JOUR
ID - 1137242
AU - Krajcarová, Lucie - Novotný, Karel - Babula, Petr - Provazník, Ivo - Prochazková, Petra - Adam, Vojtěch - Martin, Madhavi Z. - Kizek, René - Kaiser, Jozef
PY - 2013
TI - Copper Transport and Accumulation in Spruce Stems (Picea abies (L.) Karsten) Revealed by Laser-Induced Breakdown Spectroscopy
JF - International Journal of Electrochemical Science
VL - 8
IS - 4
SP - 4485-4504
EP - 4485-4504
PB - ESG
SN - 14523981
KW - Electrochemical Detection
KW - Double-pulse LIBS
KW - Fluorescence Microscopy
KW - Elemental Distribution
KW - Mass Spectrometry
UR - http://www.electrochemsci.org/papers/vol8/80404485.pdf
L2 - http://www.electrochemsci.org/papers/vol8/80404485.pdf
N2 - Laser-Induced Breakdown Spectroscopy (LIBS) in double pulse configuration (DP LIBS) was used for scanning elemental spatial distribution in annual terminal stems of spruce (Picea abies (L.) Karsten). Cross sections of stems cultivated in Cu2+ solution of different concentrations were prepared and analyzed by DP LIBS. Raster scanning with 150 mu m spatial resolution was set and 2D (2-dimentional) maps of Cu and Ca distribution were created on the basis of the data obtained. Stem parts originating in the vicinity of the implementation of the cross sections were mineralized and subsequently Cu and Ca contents were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The results provide quantitative information about overall concentration of the elements in places, where LIBS measurements were performed. The fluorescence pictures were created to compare LIBS distribution maps and the fluorescence intensity (or the increase in autofluorescence) was used for the comparison of ICP-MS quantitative results. Results from these three methods can be utilized for quantitative measurements of copper ions transport in different plant compartments in dependence on the concentration of cultivation medium and/or the time of cultivation.
ER -
KRAJCAROVÁ, Lucie, Karel NOVOTNÝ, Petr BABULA, Ivo PROVAZNÍK, Petra PROCHAZKOVÁ, Vojtěch ADAM, Madhavi Z. MARTIN, René KIZEK a Jozef KAISER. Copper Transport and Accumulation in Spruce Stems (Picea abies (L.) Karsten) Revealed by Laser-Induced Breakdown Spectroscopy. \textit{International Journal of Electrochemical Science}. Belgrade: ESG, 2013, roč.~8, č.~4, s.~4485-4504. ISSN~1452-3981.
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