a 2013

Fast Classification of Brick Samples by Combination of Principal Component Analysis and Linear Discriminant Analysis Using Standoff Laser-Induced Breakdown Spectroscopy

VÍTKOVÁ, Gabriela, Lubomír PROKEŠ, Karel NOVOTNÝ, Aleš HRDLIČKA, Jan NOVOTNÝ et. al.

Základní údaje

Originální název

Fast Classification of Brick Samples by Combination of Principal Component Analysis and Linear Discriminant Analysis Using Standoff Laser-Induced Breakdown Spectroscopy

Autoři

VÍTKOVÁ, Gabriela (203 Česká republika, domácí), Lubomír PROKEŠ (203 Česká republika, domácí), Karel NOVOTNÝ (203 Česká republika, garant, domácí), Aleš HRDLIČKA (203 Česká republika, domácí), Jan NOVOTNÝ (203 Česká republika) a Jozef KAISER (203 Česká republika)

Vydání

Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy 2013, 2013

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10406 Analytical chemistry

Stát vydavatele

Itálie

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14740/13:00070570

Organizační jednotka

Středoevropský technologický institut

Klíčová slova anglicky

Stand-off LIBS; PCA; LDA; ANN; Geomaterials; Archeology
Změněno: 14. 2. 2014 14:18, doc. Mgr. Karel Novotný, Ph.D.

Anotace

V originále

LDA is a multivariate statistical method for discrimination of objects up to a finite number of categories, based on a certain subset of all objects (training set). The principle of this method is maximizing the ratio of the between-class variance to the within-class variance. The decision rules obtained by classification of training set are later applied to the testing set. PCA was applied to reduce a dimensionality and the scores were computed from whole spectra (200 – 1000 nm) of 29 brick samples obtained by stand-off LIBS. After dividing the sample set into training and test samples first few principal components were used as inputs to LDA and the predictions of localities were computed. The results suggest that stand-off LIBS in combination with advanced statistical methods has a big potential for archaeological in-field measurements. By examining of PCA scores there was also discovered a dependence of firing temperature of bricks. Spectra of bricks fired on 300 – 1000 Celsius differs and this property is reflected significantly in only one of the principal components.

Návaznosti

ED1.1.00/02.0068, projekt VaV
Název: CEITEC - central european institute of technology