Chemical reactivity and long-range transport potential of
polycyclic aromatic hydrocarbons - a review

J 2013

Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review

KEYTE, I.J., R.M. HARRISON a Gerhard LAMMEL

Základní údaje

Originální název

Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review

Autoři

KEYTE, I.J. (826 Velká Británie a Severní Irsko), R.M. HARRISON (826 Velká Británie a Severní Irsko, garant) a Gerhard LAMMEL (276 Německo, domácí)

Vydání

Chemical Society Reviews, Cambridge, RSC Publishing, 2013, 0306-0012

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 30.425

Kód RIV

RIV/00216224:14310/13:00071064

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1039/c3cs60147a

UT WoS

000327260500009

Klíčová slova anglicky

GAS-PHASE REACTIONS; LIQUID-CHROMATOGRAPHY; SEMIVOLATILE ORGANIC-COMPOUNDS; SIMULATED ATMOSPHERIC CONDITIONS; AIRBORNE PARTICULATE MATTER; RADICAL-INITIATED REACTIONS; MS; PCBS; CONTINENTAL BOUNDARY-LAYER

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 4. 4. 2014 20:30, prof. RNDr. Luděk Bláha, Ph.D.

Anotace

V originále

Polycyclic aromatic hydrocarbons (PAHs) are of considerable concern due to their well-recognised toxicity and especially due to the carcinogenic hazard which they present. PAHs are semi-volatile and therefore partition between vapour and condensed phases in the atmosphere and both the vapour and particulate forms undergo chemical reactions. This article briefly reviews the current understanding of vapour-particle partitioning of PAHs and the PAH deposition processes, and in greater detail, their chemical reactions. PAHs are reactive towards a number of atmospheric oxidants, most notably the hydroxyl radical, ozone, the nitrate radical (NO3) and nitrogen dioxide. Rate coefficient data are reviewed for reactions of lower molecular weight PAH vapour with these species as well as for heterogeneous reactions of higher molecular weight compounds. Whereas the data for reactions of the 2-3-ring PAH vapour are quite extensive and generally consistent, such data are mostly lacking for the 4-ring PAHs and the heterogeneous rate data (5 and more rings), which are dependent on the substrate type and reaction conditions, are less comprehensive. The atmospheric reactions of PAH lead to the formation of oxy and nitro derivatives, reviewed here, too. Finally, the capacity of PAHs for long range transport and the results of numerical model studies are described. Research needs are identified.

Návaznosti

ED0001/01/01, projekt VaV

Název: CETOCOEN

EE2.3.20.0053, projekt VaV

Název: Podpora odborníků a mezinárodního networkingu v oblastech environmentálního výzkumu v ČR

LM2011028, projekt VaV

Název: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, RECETOX Národní infrastruktura pro výzkum toxických látek v prostředí

Citovat

KEYTE, I.J., R.M. HARRISON a Gerhard LAMMEL. Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review. Chemical Society Reviews. Cambridge: RSC Publishing, 2013, roč. 42, č. 24, s. 9333-9391. ISSN 0306-0012. Dostupné z: https://dx.doi.org/10.1039/c3cs60147a.

@article{1159418,
   author = {Keyte, I.J. and Harrison, R.M. and Lammel, Gerhard},
   article_location = {Cambridge},
   article_number = {24},
   doi = {http://dx.doi.org/10.1039/c3cs60147a},
   keywords = {GAS-PHASE REACTIONS; LIQUID-CHROMATOGRAPHY; SEMIVOLATILE ORGANIC-COMPOUNDS; SIMULATED ATMOSPHERIC CONDITIONS; AIRBORNE PARTICULATE MATTER; RADICAL-INITIATED REACTIONS; MS; PCBS; CONTINENTAL BOUNDARY-LAYER},
   language = {eng},
   issn = {0306-0012},
   journal = {Chemical Society Reviews},
   title = {Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review},
   volume = {42},
   year = {2013}
}

TY  - JOUR
ID  - 1159418
AU  - Keyte, I.J. - Harrison, R.M. - Lammel, Gerhard
PY  - 2013
TI  - Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review
JF  - Chemical Society Reviews
VL  - 42
IS  - 24
SP  - 9333-9391
EP  - 9333-9391
PB  - RSC Publishing
SN  - 03060012
KW  - GAS-PHASE REACTIONS
KW  - LIQUID-CHROMATOGRAPHY
KW  - SEMIVOLATILE ORGANIC-COMPOUNDS
KW  - SIMULATED ATMOSPHERIC CONDITIONS
KW  - AIRBORNE PARTICULATE MATTER
KW  - RADICAL-INITIATED REACTIONS
KW  - MS
KW  - PCBS
KW  - CONTINENTAL BOUNDARY-LAYER
N2  - Polycyclic aromatic hydrocarbons (PAHs) are of considerable concern due to their well-recognised toxicity and especially due to the carcinogenic hazard which they present. PAHs are semi-volatile and therefore partition between vapour and condensed phases in the atmosphere and both the vapour and particulate forms undergo chemical reactions. This article briefly reviews the current understanding of vapour-particle partitioning of PAHs and the PAH deposition processes, and in greater detail, their chemical reactions. PAHs are reactive towards a number of atmospheric oxidants, most notably the hydroxyl radical, ozone, the nitrate radical (NO3) and nitrogen dioxide. Rate coefficient data are reviewed for reactions of lower molecular weight PAH vapour with these species as well as for heterogeneous reactions of higher molecular weight compounds. Whereas the data for reactions of the 2-3-ring PAH vapour are quite extensive and generally consistent, such data are mostly lacking for the 4-ring PAHs and the heterogeneous rate data (5 and more rings), which are dependent on the substrate type and reaction conditions, are less comprehensive. The atmospheric reactions of PAH lead to the formation of oxy and nitro derivatives, reviewed here, too. Finally, the capacity of PAHs for long range transport and the results of numerical model studies are described. Research needs are identified.
ER  -

KEYTE, I.J., R.M. HARRISON a Gerhard LAMMEL. Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review. \textit{Chemical Society Reviews}. Cambridge: RSC Publishing, 2013, roč.~42, č.~24, s.~9333-9391. ISSN~0306-0012. Dostupné z: https://dx.doi.org/10.1039/c3cs60147a.

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