Generation of AupAgqTer clusters via laser ablation synthesis
using Au-Ag- Te nano-composite as precursor: Laser desorption
ionisation with quadrupole ion trap time-of-flight mass
spectrometry

J 2014

Generation of AupAgqTer clusters via laser ablation synthesis using Au-Ag- Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL

Základní údaje

Originální název

Generation of AupAgqTer clusters via laser ablation synthesis using Au-Ag- Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry

Autoři

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL

Vydání

Rapid Communications in Mass Spectrometry, Wiley, 2014, 0951-4198

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.253

Kód RIV

RIV/00216224:14310/14:00075214

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1002/rcm.6936

UT WoS

000338767000004

EID Scopus

2-s2.0-84901930620

Klíčová slova anglicky

Mass spectrometry; Tellurium; nano-composite

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 27. 4. 2015 14:55, Ing. Andrea Mikešková

Anotace

V originále

RATIONALE: Metal tellurides show applications in various fields of science and technology while only limited number of gold-silver tellurides is known. Laser ablation synthesis (LAS) method allows preparation of nano-materials from solid substrates. Therefore, this method was selected to synthesize gold-silver tellurides. METHODS: Laser desorption ionisation quadruple ion trap time-of-flight mass spectrometry (LDI QIT TOF MS) was used for generation of new AupAgqTer clusters. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were used to characterize the materials. The stoichiometry of clusters generated was determined via collision-induced dissociation (CID) and modeling of isotopic patterns. RESULTS: Chemisorption of gold and silver nano-particles on tellurium powder leads to the formation of a new kind of Au-Ag-Te nano-composite. The LDI of this nano-composite leads to the formation of 9 unary (Agq, Ter), 40 binary (AupTer and AgpTer) and 78 ternary clusters. The stoichiometry of novel AupAgqTer clusters is reported here for the first time. CONCLUSIONS: New Au-Ag-Te nano-composite was found as more suitable precursor for clusters generation than the mixtures of the elements. TOF MS was demonstrated to be a useful technique to follow the generation of gold-silver tellurides. Knowledge of clusters stoichiometry might accelerate further development of novel high-tech materials such as chalcogenide glasses.

Návaznosti

ED2.1.00/03.0086, projekt VaV

Název: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL. Generation of AupAgqTer clusters via laser ablation synthesis using Au-Ag- Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry. Rapid Communications in Mass Spectrometry. Wiley, 2014, roč. 28, č. 14, s. 1601-1608. ISSN 0951-4198. Dostupné z: https://doi.org/10.1002/rcm.6936.

@article{1173224,
   author = {Mawale, Ravi and Amato, Filippo and Alberti, Milan and Havel, Josef},
   article_number = {14},
   doi = {https://doi.org/10.1002/rcm.6936},
   keywords = {Mass spectrometry; Tellurium; nano-composite},
   language = {eng},
   issn = {0951-4198},
   journal = {Rapid Communications in Mass Spectrometry},
   title = {Generation of AupAgqTer clusters via laser ablation synthesis using Au-Ag- Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry},
   volume = {28},
   year = {2014}
}

TY  - JOUR
ID  - 1173224
AU  - Mawale, Ravi - Amato, Filippo - Alberti, Milan - Havel, Josef
PY  - 2014
TI  - Generation of AupAgqTer clusters via laser ablation synthesis using Au-Ag- Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry
JF  - Rapid Communications in Mass Spectrometry
VL  - 28
IS  - 14
SP  - 1601-1608
EP  - 1601-1608
PB  - Wiley
SN  - 09514198
KW  - Mass spectrometry
KW  - Tellurium
KW  - nano-composite
N2  - RATIONALE: Metal tellurides show applications in various fields of science and technology while only limited number of gold-silver tellurides is known. Laser ablation synthesis (LAS) method allows preparation of nano-materials from solid substrates. Therefore, this method was selected to synthesize gold-silver tellurides. METHODS: Laser desorption ionisation quadruple ion trap time-of-flight mass spectrometry (LDI QIT TOF MS) was used for generation of new AupAgqTer clusters. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were used to characterize the materials. The stoichiometry of clusters generated was determined via collision-induced dissociation (CID) and modeling of isotopic patterns. RESULTS: Chemisorption of gold and silver nano-particles on tellurium powder leads to the formation of a new kind of Au-Ag-Te nano-composite. The LDI of this nano-composite leads to the formation of 9 unary (Agq, Ter), 40 binary (AupTer and AgpTer) and 78 ternary clusters. The stoichiometry of novel AupAgqTer clusters is reported here for the first time. CONCLUSIONS: New Au-Ag-Te nano-composite was found as more suitable precursor for clusters generation than the mixtures of the elements. TOF MS was demonstrated to be a useful technique to follow the generation of gold-silver tellurides. Knowledge of clusters stoichiometry might accelerate further development of novel high-tech materials such as chalcogenide glasses.
ER  -

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL. Generation of AupAgqTer clusters via laser ablation synthesis using Au-Ag- Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry. \textit{Rapid Communications in Mass Spectrometry}. Wiley, 2014, roč.~28, č.~14, s.~1601-1608. ISSN~0951-4198. Dostupné z: https://doi.org/10.1002/rcm.6936.

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