Factors affecting the Nd3+ (REE3+) luminescence of minerals

J 2013

Factors affecting the Nd3+ (REE3+) luminescence of minerals

LENZ, Christoph; Dominik TALLA; Katja RUSCHEL; Radek ŠKODA; Jens GOETZE et al.

Základní údaje

Originální název

Factors affecting the Nd3+ (REE3+) luminescence of minerals

Autoři

LENZ, Christoph; Dominik TALLA; Katja RUSCHEL; Radek ŠKODA; Jens GOETZE a Lutz NASDALA

Vydání

Mineralogy and Petrology, Austria, Springer Verlag, 2013, 0930-0708

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10500 1.5. Earth and related environmental sciences

Stát vydavatele

Rakousko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.598

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/13:00072835

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1007/s00710-013-0286-2

UT WoS

000321918700006

Klíčová slova anglicky

RARE-EARTH ELEMENTS; SITE-SELECTIVE SPECTROSCOPY; RESOLUTION SPECTROMETRIC ANALYSIS; BACKSCATTERED ELECTRON IMAGES; CATHODOLUMINESCENCE CL; ACTIVATED CATHODOLUMINESCENCE; CRYSTAL-CHEMISTRY; HIGH-TEMPERATURE; SOLID-SOLUTIONS; MONAZITE

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 4. 4. 2014 10:44, Ing. Andrea Mikešková

Anotace

V originále

In this paper, possibilities and limits of the application of REE3+ luminescence (especially the Nd3+ F-4(3/2) -> I-4(9/2) emission) as structural probe are evaluated. Important factors controlling the Nd3+ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO4), xenotime-(Y) (YPO4),monazite-(Ce)(CePO4) and their synthetic analogues. Based on these examples we review in short that (1) REE3+ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE3+-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd3+-related centres are found to be promising candidates.

Návaznosti

EE2.3.20.0052, projekt VaV

Název: Výzkumný tým pro ukládání radioaktivních odpadů a jadernou bezpečnost

Citovat

LENZ, Christoph; Dominik TALLA; Katja RUSCHEL; Radek ŠKODA; Jens GOETZE a Lutz NASDALA. Factors affecting the Nd3+ (REE3+) luminescence of minerals. Mineralogy and Petrology. Austria: Springer Verlag, 2013, roč. 107, č. 3, s. 415-428. ISSN 0930-0708. Dostupné z: https://doi.org/10.1007/s00710-013-0286-2.

@article{1173942,
   author = {Lenz, Christoph and Talla, Dominik and Ruschel, Katja and Škoda, Radek and Goetze, Jens and Nasdala, Lutz},
   article_location = {Austria},
   article_number = {3},
   doi = {https://doi.org/10.1007/s00710-013-0286-2},
   keywords = {RARE-EARTH ELEMENTS; SITE-SELECTIVE SPECTROSCOPY; RESOLUTION SPECTROMETRIC ANALYSIS; BACKSCATTERED ELECTRON IMAGES; CATHODOLUMINESCENCE CL; ACTIVATED CATHODOLUMINESCENCE; CRYSTAL-CHEMISTRY; HIGH-TEMPERATURE; SOLID-SOLUTIONS; MONAZITE},
   language = {eng},
   issn = {0930-0708},
   journal = {Mineralogy and Petrology},
   title = {Factors affecting the Nd3+ (REE3+) luminescence of minerals},
   volume = {107},
   year = {2013}
}

TY  - JOUR
ID  - 1173942
AU  - Lenz, Christoph - Talla, Dominik - Ruschel, Katja - Škoda, Radek - Goetze, Jens - Nasdala, Lutz
PY  - 2013
TI  - Factors affecting the Nd3+ (REE3+) luminescence of minerals
JF  - Mineralogy and Petrology
VL  - 107
IS  - 3
SP  - 415-428
EP  - 415-428
PB  - Springer Verlag
SN  - 09300708
KW  - RARE-EARTH ELEMENTS
KW  - SITE-SELECTIVE SPECTROSCOPY
KW  - RESOLUTION SPECTROMETRIC ANALYSIS
KW  - BACKSCATTERED ELECTRON IMAGES
KW  - CATHODOLUMINESCENCE CL
KW  - ACTIVATED CATHODOLUMINESCENCE
KW  - CRYSTAL-CHEMISTRY
KW  - HIGH-TEMPERATURE
KW  - SOLID-SOLUTIONS
KW  - MONAZITE
N2  - In this paper, possibilities and limits of the application of REE3+ luminescence (especially the Nd3+ F-4(3/2) -> I-4(9/2) emission) as structural probe are evaluated. Important factors controlling the Nd3+ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO4), xenotime-(Y) (YPO4),monazite-(Ce)(CePO4) and their synthetic analogues. Based on these examples we review in short that (1) REE3+ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE3+-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd3+-related centres are found to be promising candidates.
ER  -

LENZ, Christoph; Dominik TALLA; Katja RUSCHEL; Radek ŠKODA; Jens GOETZE a Lutz NASDALA. Factors affecting the Nd3+ (REE3+) luminescence of minerals. \textit{Mineralogy and Petrology}. Austria: Springer Verlag, 2013, roč.~107, č.~3, s.~415-428. ISSN~0930-0708. Dostupné z: https://doi.org/10.1007/s00710-013-0286-2.

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