| LEJČEK, Pavel, Lei ZHENG, Siegfried HOFMANN and Mojmír ŠOB. Applied Thermodynamics: Grain Boundary Segregation. Entropy. Basel (Schwitzerland): MDPI AG, POSTFACH, 2014, vol. 16, No 3, p. 1462-1483. ISSN 1099-4300. Available from: https://dx.doi.org/10.3390/e16031462. |
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@article{1209895,
author = {Lejček, Pavel and Zheng, Lei and Hofmann, Siegfried and Šob, Mojmír},
article_location = {Basel (Schwitzerland)},
article_number = {3},
doi = {http://dx.doi.org/10.3390/e16031462},
keywords = {APPLIED TENSILE-STRESS; LOW-ALLOY STEEL; INTERFACIAL SEGREGATION; SOLUTE INTERACTION; ALPHA-IRON; PHOSPHORUS; ANISOTROPY; EMBRITTLEMENT; ENTHALPY},
language = {eng},
issn = {1099-4300},
journal = {Entropy},
title = {Applied Thermodynamics: Grain Boundary Segregation},
url = {http://www.mdpi.com/1099-4300/16/3/1462},
volume = {16},
year = {2014}
}
TY - JOUR
ID - 1209895
AU - Lejček, Pavel - Zheng, Lei - Hofmann, Siegfried - Šob, Mojmír
PY - 2014
TI - Applied Thermodynamics: Grain Boundary Segregation
JF - Entropy
VL - 16
IS - 3
SP - 1462-1483
EP - 1462-1483
PB - MDPI AG, POSTFACH
SN - 10994300
KW - APPLIED TENSILE-STRESS
KW - LOW-ALLOY STEEL
KW - INTERFACIAL SEGREGATION
KW - SOLUTE INTERACTION
KW - ALPHA-IRON
KW - PHOSPHORUS
KW - ANISOTROPY
KW - EMBRITTLEMENT
KW - ENTHALPY
UR - http://www.mdpi.com/1099-4300/16/3/1462
L2 - http://www.mdpi.com/1099-4300/16/3/1462
N2 - Chemical composition of interfaces-free surfaces and grain boundaries-is generally described by the Langmuir-McLean segregation isotherm controlled by Gibbs energy of segregation. Various components of the Gibbs energy of segregation, the standard and the excess ones as well as other thermodynamic state functions-enthalpy, entropy and volume-of interfacial segregation are derived and their physical meaning is elucidated. The importance of the thermodynamic state functions of grain boundary segregation, their dependence on volume solid solubility, mutual solute-solute interaction and pressure effect in ferrous alloys is demonstrated
ER -
LEJČEK, Pavel, Lei ZHENG, Siegfried HOFMANN and Mojmír ŠOB. Applied Thermodynamics: Grain Boundary Segregation. \textit{Entropy}. Basel (Schwitzerland): MDPI AG, POSTFACH, 2014, vol.~16, No~3, p.~1462-1483. ISSN~1099-4300. Available from: https://dx.doi.org/10.3390/e16031462.
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