Excitation of mercury atoms in nitrogen post-discharge

D 2014

Excitation of mercury atoms in nitrogen post-discharge

KRČMA, František; Ivana BOCKOVÁ; Věra MAZÁNKOVÁ; Ivo SOURAL; Aleš HRDLIČKA et al.

Základní údaje

Originální název

Excitation of mercury atoms in nitrogen post-discharge

Název česky

Exitace atomů rtuti v dohasínajícím dusíkovém výboji

Autoři

KRČMA, František; Ivana BOCKOVÁ; Věra MAZÁNKOVÁ; Ivo SOURAL; Aleš HRDLIČKA a Viktor KANICKÝ

Vydání

Bristol, 4th International Workshop & Summer School on Plasma Physics 2010, od s. 1-10, 10 s. 2014

Nakladatel

IOP Publishing

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Forma vydání

elektronická verze "online"

Odkazy

odkaz na článek

Označené pro přenos do RIV

Organizační jednotka

Středoevropský technologický institut

ISSN

DOI

https://doi.org/10.1088/1742-6596/516/1/012005

UT WoS

000344464700005

Klíčová slova česky

poolingové reakce; růžové dohasínání; n-2; chemie; kinetika; ionizace; výboj; směsi; model

Klíčová slova anglicky

energy-pooling reactions; pink afterglow; n-2; chemistry; kinetics; ionization; discharge; mixtures;model

Štítky

neMU, podil

Změněno: 27. 3. 2015 12:29, Martina Prášilová

Anotace

V originále

The work presents results obtained during spectroscopic observations of nitrogen DC flowing post-discharges at the total gas pressure of 1000 Pa and at the discharge current of 100 mA. Mercury traces were introduced into the system using auxiliary pure nitrogen flow enriched by mercury vapor. A very low mercury concentration of 3.7 ppb was introduced into the system before the active discharge. The strong quenching of nitrogen pink afterglow was observed but no mercury lines were recorded. Moreover, the vibrational distributions of nitrogen excited states were nearly unchanged. Based on these results, the new experimental set up was created. The introduction point of mercury vapor with higher concentration of 600 ppm was movable during the post discharge up to decay time of 40 ms. Besides three nitrogen spectral systems (first and second positive and first negative), NO beta and NO gamma bands, the mercury line at 254 nm was recorded at these conditions. Its intensity was dependent on the mercury vapor introduction position as well as on the mercury concentration. No other mercury lines were observed. The creation of mercury P-3(1) state that is the upper state of the observed mercury spectral line is possible by the resonance excitation energy transfer form vibrationally excited nitrogen ground state N-2 (X (1)Sigma(+)(g), v = 19). The observed results should form a background for the development of a new titration technique used for the highly vibrationally excited nitrogen ground state molecules determination.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

GA202/05/0111, projekt VaV

Název: Studium kinetických procesů v dohasínajícím dusíkovém plazmatu s ohledem na jejich využití v chemické analýze

Investor: Grantová agentura ČR, Studium kinetických procesů v dohasínajícím dusíkovém plazmatu s ohledem na jejich využití v chemické analýze

GA202/08/1106, projekt VaV

Název: Studium nerovnovážné kinetiky plazmochemických reakcí v atmosférických plynech za sníženého tlaku s ohledem na využití v analytické chemii

Investor: Grantová agentura ČR, Studium nerovnovážné kinetiky plazmochemických reakcí v atmosférických plynech za sníženého tlaku s ohledem na využití v analytické chemii

Citovat

KRČMA, František; Ivana BOCKOVÁ; Věra MAZÁNKOVÁ; Ivo SOURAL; Aleš HRDLIČKA a Viktor KANICKÝ. Excitation of mercury atoms in nitrogen post-discharge. Online. In 4th International Workshop & Summer School on Plasma Physics 2010. Bristol: IOP Publishing, 2014, s. 1-10. ISSN 1742-6588. Dostupné z: https://doi.org/10.1088/1742-6596/516/1/012005.

@inproceedings{1213587,
   author = {Krčma, František and Bocková, Ivana and Mazánková, Věra and Soural, Ivo and Hrdlička, Aleš and Kanický, Viktor},
   address = {Bristol},
   booktitle = {4th International Workshop & Summer School on Plasma Physics 2010},
   doi = {https://doi.org/10.1088/1742-6596/516/1/012005},
   keywords = {energy-pooling reactions; pink afterglow; n-2; chemistry; kinetics; ionization; discharge; mixtures;model},
   howpublished = {elektronická verze "online"},
   language = {eng},
   location = {Bristol},
   pages = {1-10},
   publisher = {IOP Publishing},
   title = {Excitation of mercury atoms in nitrogen post-discharge},
   url = {http://iopscience.iop.org/1742-6596/516/1/012005/pdf/1742-6596_516_1_012005.pdf},
   year = {2014}
}

TY  - CONF
ID  - 1213587
AU  - Krčma, František - Bocková, Ivana - Mazánková, Věra - Soural, Ivo - Hrdlička, Aleš - Kanický, Viktor
PY  - 2014
TI  - Excitation of mercury atoms in nitrogen post-discharge
PB  - IOP Publishing
CY  - Bristol
KW  - energy-pooling reactions
KW  - pink afterglow
KW  - n-2
KW  - chemistry
KW  - kinetics
KW  - ionization
KW  - discharge
KW  - mixtures;model
UR  - http://iopscience.iop.org/1742-6596/516/1/012005/pdf/1742-6596_516_1_012005.pdf
L2  - http://iopscience.iop.org/1742-6596/516/1/012005/pdf/1742-6596_516_1_012005.pdf
N2  - The work presents results obtained during spectroscopic observations of nitrogen DC flowing post-discharges at the total gas pressure of 1000 Pa and at the discharge current of 100 mA. Mercury traces were introduced into the system using auxiliary pure nitrogen flow enriched by mercury vapor. A very low mercury concentration of 3.7 ppb was introduced into the system before the active discharge. The strong quenching of nitrogen pink afterglow was observed but no mercury lines were recorded. Moreover, the vibrational distributions of nitrogen excited states were nearly unchanged. Based on these results, the new experimental set up was created. The introduction point of mercury vapor with higher concentration of 600 ppm was movable during the post discharge up to decay time of 40 ms. Besides three nitrogen spectral systems (first and second positive and first negative), NO beta and NO gamma bands, the mercury line at 254 nm was recorded at these conditions. Its intensity was dependent on the mercury vapor introduction position as well as on the mercury concentration. No other mercury lines were observed. The creation of mercury P-3(1) state that is the upper state of the observed mercury spectral line is possible by the resonance excitation energy transfer form vibrationally excited nitrogen ground state N-2 (X (1)Sigma(+)(g), v = 19). The observed results should form a background for the development of a new titration technique used for the highly vibrationally excited nitrogen ground state molecules determination.
ER  -

KRČMA, František; Ivana BOCKOVÁ; Věra MAZÁNKOVÁ; Ivo SOURAL; Aleš HRDLIČKA a Viktor KANICKÝ. Excitation of mercury atoms in nitrogen post-discharge. Online. In \textit{4th International Workshop \&{} Summer School on Plasma Physics 2010}. Bristol: IOP Publishing, 2014, s.~1-10. ISSN~1742-6588. Dostupné z: https://doi.org/10.1088/1742-6596/516/1/012005.

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