Generation of novel AupAgqTer clusters via laser ablation
synthesis using Au-Ag-Te nano-composite as precursor: Laser
desorption ionisation with quadrupole ion trap time-of-flight
mass spectrometry

k 2014

Generation of novel AupAgqTer clusters via laser ablation synthesis using Au-Ag-Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL

Základní údaje

Originální název

Generation of novel AupAgqTer clusters via laser ablation synthesis using Au-Ag-Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry

Autoři

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL

Vydání

ESAS 2014, Prague, Czech Republic, 2014

Další údaje

Jazyk

angličtina

Typ výsledku

Prezentace na konferencích

Obor

10406 Analytical chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/14:00074302

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

mass spectrometry; laser ablation synthesis; clusters

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 28. 4. 2015 09:28, Ing. Andrea Mikešková

Anotace

V originále

Gold, tellurium and silver are found in nature either in their native state or in alloy with other metals. Gold tellurides are known as various minerals such as calaverite, krennerite (AuTe2) and montebrazite (Au2Te3). Silver tellurides are known as hessite (Ag2Te) and empressite (AgTe). Sylvanites (AuAgTe4) and mutmannite (AuAgTe2) are the ores of gold, silver and telluride. Laser ablation synthesis (LAS) was proved to be powerful technique for the generation and study of clusters from various materials. In addition, structural fragments of solid materials have been identified using laser desorption ionisation time-of-flight mass spectrometry (LDI-TOF-MS) for example. The aim of this work was to study the formation of binary AupAgq, AgqTer, AupTer and ternary AupAgqTer clusters generated via LAS of Au-Ag-Te mixture and/or composite material. Gold and silver nanoparticles were mixed with powder of metallic tellurium in different ratio and formation of clusters was followed with a mass spectrometer equipped with quadrupole ion trap, reflectron and time of flight analyser. The stoichiometry of the detected AupAgqTer clusters was found via modelling of the isotopic patterns and around 70 different binary and ternary clusters were identified. Generation of AupAgqTer clusters and knowledge of the stoichiometry might be important for the development of new materials with specific properties.

Návaznosti

ED2.1.00/03.0086, projekt VaV

Název: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

GA13-05082S, projekt VaV

Název: Analýza a aplikace plazmatických procesů pro přípravu tenkých vrstev amorfních chalkogenidů

Investor: Grantová agentura ČR, Analýza a aplikace plazmatických procesů pro přípravu tenkých vrstev amorfních chalkogenidů

Citovat

MAWALE, Ravi; Filippo AMATO; Milan ALBERTI a Josef HAVEL. Generation of novel AupAgqTer clusters via laser ablation synthesis using Au-Ag-Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry. In ESAS 2014, Prague, Czech Republic. 2014.

@proceedings{1216147,
   author = {Mawale, Ravi and Amato, Filippo and Alberti, Milan and Havel, Josef},
   booktitle = {ESAS 2014, Prague, Czech Republic},
   keywords = {mass spectrometry; laser ablation synthesis; clusters},
   language = {eng},
   title = {Generation of novel AupAgqTer clusters via laser ablation synthesis using Au-Ag-Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry},
   year = {2014}
}

TY  - CONF
ID  - 1216147
AU  - Mawale, Ravi - Amato, Filippo - Alberti, Milan - Havel, Josef
PY  - 2014
TI  - Generation of novel AupAgqTer clusters via laser ablation synthesis using Au-Ag-Te nano-composite as precursor: Laser desorption ionisation with quadrupole ion trap time-of-flight mass spectrometry
KW  - mass spectrometry
KW  - laser ablation synthesis
KW  - clusters
N2  - Gold, tellurium and silver are found in nature either in their native state or in alloy with other metals. Gold tellurides are known as various minerals such as calaverite, krennerite (AuTe2) and montebrazite (Au2Te3). Silver tellurides are known as hessite (Ag2Te) and empressite (AgTe). Sylvanites (AuAgTe4) and mutmannite (AuAgTe2) are the ores of gold, silver and telluride. Laser ablation synthesis (LAS) was proved to be powerful technique for the generation and study of clusters from various materials. In addition, structural fragments of solid materials have been identified using laser desorption ionisation time-of-flight mass spectrometry (LDI-TOF-MS) for example. The aim of this work was to study the formation of binary AupAgq, AgqTer, AupTer and ternary AupAgqTer clusters generated via LAS of Au-Ag-Te mixture and/or composite material. Gold and silver nanoparticles were mixed with powder of metallic tellurium in different ratio and formation of clusters was followed with a mass spectrometer equipped with quadrupole ion trap, reflectron and time of flight analyser. The stoichiometry of the detected AupAgqTer clusters was found via modelling of the isotopic patterns and around 70 different binary and ternary clusters were identified. Generation of AupAgqTer clusters and knowledge of the stoichiometry might be important for the development of new materials with specific properties.
ER  -

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