On the reactions of chlorodithiophosphoric acid
pyridiniumbetaine with polyfunctional nucleophiles. Part IV:
Reactions with thiosemicarbazide monoaryl derivatives

J 2015

On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives

ŠEVČÍK, Richard a Jiří PŘÍHODA

Základní údaje

Originální název

On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives

Autoři

ŠEVČÍK, Richard a Jiří PŘÍHODA

Vydání

Polyhedron, Elsevier, 2015, 0277-5387

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.108

Kód RIV

RIV/00216224:14310/15:00082257

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1016/j.poly.2014.08.022

UT WoS

000347582900022

EID Scopus

2-s2.0-84907584664

Klíčová slova anglicky

Five-membered heterocycle; Thiosemicarbazide; Chlorodithiophosphoric acid pyridiniumbetaine; X-ray analysis; NMR

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 3. 2018 10:12, RNDr. Richard Ševčík, Ph.D.

Anotace

V originále

In connection with our previous research, reactions of chlorodithiophosphoric acid pyridiniumbetaine, py.PS2Cl (I), with monoaryl thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = phenyl, 4-nitrophenyl) were studied with the aim to prepare new heterocyclic compounds. All reactions were carried out in acetonitrile in the presence of pyridine as an HCl acceptor. New compounds, pyridinium salts of 4-phenyl-3-sulfido-3,5-dithioxo-1,2,4,3k5-triazaphospholidine (II) and 4-(4-nitrophenyl)-3-sulfido-3, 5-dithioxo-1,2,4,3k5-triazaphospholidine (III) were prepared. 31P NMR, FT-IR, Raman spectroscopy, and X-ray diffraction analysis revealed their molecular structures consisting of pyridinium cation and fivemembered P–N–N–C–N heterocyclic anion bearing relevant aryl group.

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

ŠEVČÍK, Richard a Jiří PŘÍHODA. On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives. Polyhedron. Elsevier, 2015, roč. 85, January, s. 161-164. ISSN 0277-5387. Dostupné z: https://doi.org/10.1016/j.poly.2014.08.022.

@article{1216842,
   author = {Ševčík, Richard and Příhoda, Jiří},
   article_number = {January},
   doi = {https://doi.org/10.1016/j.poly.2014.08.022},
   keywords = {Five-membered heterocycle; Thiosemicarbazide; Chlorodithiophosphoric acid pyridiniumbetaine; X-ray analysis; NMR},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives},
   url = {http://www.sciencedirect.com/science/article/pii/S0277538714005440},
   volume = {85},
   year = {2015}
}

TY  - JOUR
ID  - 1216842
AU  - Ševčík, Richard - Příhoda, Jiří
PY  - 2015
TI  - On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives
JF  - Polyhedron
VL  - 85
IS  - January
SP  - 161-164
EP  - 161-164
PB  - Elsevier
SN  - 02775387
KW  - Five-membered heterocycle
KW  - Thiosemicarbazide
KW  - Chlorodithiophosphoric acid pyridiniumbetaine
KW  - X-ray analysis
KW  - NMR
UR  - http://www.sciencedirect.com/science/article/pii/S0277538714005440
L2  - http://www.sciencedirect.com/science/article/pii/S0277538714005440
N2  - In connection with our previous research, reactions of chlorodithiophosphoric acid pyridiniumbetaine, py.PS2Cl (I), with monoaryl thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = phenyl, 4-nitrophenyl) were studied with the aim to prepare new heterocyclic compounds. All reactions were carried out in acetonitrile in the presence of pyridine as an HCl acceptor. New compounds, pyridinium salts of 4-phenyl-3-sulfido-3,5-dithioxo-1,2,4,3k5-triazaphospholidine (II) and 4-(4-nitrophenyl)-3-sulfido-3, 5-dithioxo-1,2,4,3k5-triazaphospholidine (III) were prepared. 31P NMR, FT-IR, Raman spectroscopy, and X-ray diffraction analysis revealed their molecular structures consisting of pyridinium cation and fivemembered P–N–N–C–N heterocyclic anion bearing relevant aryl group.
ER  -

ŠEVČÍK, Richard a Jiří PŘÍHODA. On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives. \textit{Polyhedron}. Elsevier, 2015, roč.~85, January, s.~161-164. ISSN~0277-5387. Dostupné z: https://doi.org/10.1016/j.poly.2014.08.022.

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