Method of production of ethane dinitrile by oxidation of
hydrogen cyanide

P 2015

Method of production of ethane dinitrile by oxidation of hydrogen cyanide

PAZDERA, Pavel, Josef HAVEL, Karel ZELINKA a Jan ŠIMBERA

Základní údaje

Originální název

Method of production of ethane dinitrile by oxidation of hydrogen cyanide

Autoři

PAZDERA, Pavel (203 Česká republika, garant, domácí), Josef HAVEL (203 Česká republika, domácí), Karel ZELINKA (203 Česká republika, domácí) a Jan ŠIMBERA (203 Česká republika, domácí)

Vydání

Číslo: AU 2012350439, Vydavatel: Australian patent office, Název vlastníka: Masarykova univerzita, 2015

Další údaje

Jazyk

angličtina

Typ výsledku

Patent

Obor

10401 Organic chemistry

Stát vydavatele

Austrálie

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Kód RIV

RIV/00216224:14310/15:00081738

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.13140/RG.2.1.1394.3845

Klíčová slova anglicky

Hydrogen cyanide; cyanogen; supported binary catalytic system; green

Štítky

AKR, rivok

Změněno: 7. 4. 2016 12:54, Ing. Andrea Mikešková

Anotace

V originále

The present invention provides a method of production of ethane dinitrile (CN)2 by oxidation of hydrogen cyanide HCN, wherein hydrogen cyanide is oxidized on a catalytic system Fem+/Cun+, wherein m has the value of 2 or 3, n has the value of 1 or 2, wherein the catalytic system is supported on a polymeric organic cation exchanger, wherein the oxidation reaction is carried out in an organic solvent, or in a homogeneous or heterogeneous mixture of an organic solvent with water, at the temperature in the range of 5 °C to 65 °C, using an oxygen-containing oxidizing agent selected from the group containing oxygen, air, hydrogen peroxide or its mono- or di-substituted alkyl or acyl derivates selected from the group including tert-butyl hydroperoxide, benzoyl hydroperoxide, dibenzoyl peroxide, di-tert-butyl peroxide, di-(2-ethylhexyl) peroxydicarbonate.

Návaznosti

2A-1TP1/090, projekt VaV

Název: Nové katalyzátory a činidla pro udržitelné zelené syntézy a kombinatoriální syntézy.

Investor: Ministerstvo průmyslu a obchodu ČR, Nové katalyzátory a činidla pro udržitelné zelené syntézy a kombinatoriální syntézy

Citovat

PAZDERA, Pavel, Josef HAVEL, Karel ZELINKA a Jan ŠIMBERA. Method of production of ethane dinitrile by oxidation of hydrogen cyanide. 2015. Patent. Číslo: AU 2012350439. Vydavatel: Australian patent office. Název vlastníka: Masarykova univerzita. Datum registrace: 11. 12. 2012. Datum přijetí: 7. 5. 2015. Dostupné z: https://dx.doi.org/10.13140/RG.2.1.1394.3845.

@misc{1301135,
   author = {Pazdera, Pavel and Havel, Josef and Zelinka, Karel and Šimbera, Jan},
   doi = {http://dx.doi.org/10.13140/RG.2.1.1394.3845},
   keywords = {Hydrogen cyanide; cyanogen; supported binary catalytic system; green},
   language = {eng},
   title = {Method of production of ethane dinitrile by oxidation of hydrogen cyanide},
   url = {https://www.researchgate.net/publication/273137515_Method_of_production_of_ethane_dinitrile_by_oxidation_of_hydrogen_cyanide},
   year = {2015}
}

TY  - PAT
ID  - 1301135
AU  - Pazdera, Pavel - Havel, Josef - Zelinka, Karel - Šimbera, Jan
PY  - 2015
TI  - Method of production of ethane dinitrile by oxidation of hydrogen cyanide
KW  - Hydrogen cyanide
KW  - cyanogen
KW  - supported binary catalytic system
KW  - green
UR  - https://www.researchgate.net/publication/273137515_Method_of_production_of_ethane_dinitrile_by_oxidation_of_hydrogen_cyanide
L2  - https://www.researchgate.net/publication/273137515_Method_of_production_of_ethane_dinitrile_by_oxidation_of_hydrogen_cyanide
N2  - The present invention provides a method of production of ethane dinitrile (CN)2 by oxidation of hydrogen cyanide HCN, wherein hydrogen cyanide is oxidized on a catalytic system Fem+/Cun+, wherein m has the value of 2 or 3, n has the value of 1 or 2, wherein the catalytic system is supported on a polymeric organic cation exchanger, wherein the oxidation reaction is carried out in an organic solvent, or in a homogeneous or heterogeneous mixture of an organic solvent with water, at the temperature in the range of 5 °C to 65 °C, using an oxygen-containing oxidizing agent selected from the group containing oxygen, air, hydrogen peroxide or its mono- or di-substituted alkyl or acyl derivates selected from the group including tert-butyl hydroperoxide, benzoyl hydroperoxide, dibenzoyl peroxide, di-tert-butyl peroxide, di-(2-ethylhexyl) peroxydicarbonate.
ER  -

PAZDERA, Pavel, Josef HAVEL, Karel ZELINKA a Jan ŠIMBERA. \textit{Method of production of ethane dinitrile by oxidation of hydrogen cyanide}. 2015. Patent. Číslo: AU 2012350439. Vydavatel: Australian patent office. Název vlastníka: Masarykova univerzita. Datum registrace: 11. 12. 2012. Datum přijetí: 7. 5. 2015. Dostupné z: https://dx.doi.org/10.13140/RG.2.1.1394.3845.

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